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This book provides a comprehensive overview of nucleophilic aromatic substitutions, focusing on the mechanistic and synthetic features that govern these reactions. The first chapter presents a detailed mechanistic analysis of the factors determining the feasibility of SNAr substitutions, providing decisive information to predict regioselectivity of many reactions and to define the conditions for concerted SNAr processes. Reflecting the key role played by these species as intermediates in most SNAr reactions, chapter 2 then discusses the chemistry of anionic sigma-complexes. Chapter 3 describes the concept of superelectrophilicity in SNAr substitutions, as it has recently emerged from the rea...
World-class science and technology developed in the Soviet Union during Stalin's dictatorial rule under conditions of political violence, lack of international contacts, and severe restrictions on the freedom of information. Stalin's Great Science: The Times and Adventures of Soviet Physicists is an invaluable book that investigates this paradoxical success by following the lives and work of Soviet scientists ? including Nobel Prize-winning physicists Kapitza, Landau, and others ? throughout the turmoil of wars, revolutions, and repression that characterized the first half of Russia's twentieth century.The book examines how scientists operated within the Soviet political order, communicated ...
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Established in 1960, Advances in Heterocyclic Chemistry is the definitive serial in the area—one of great importance to organic chemists, polymer chemists, and many biological scientists. Written by established authorities in the field, the comprehensive reviews combine descriptive chemistry and mechanistic insight and yield an understanding of how the chemistry drives the properties. - Provides up-to-date material on a fast growing and highly topical subject area - Contains the latest research covering a wide variety of heterocyclic topics - Written by leading authorities and designed as a handbook for students and industry and academic researchers
Now in its second completely revised and expanded edition. Written by the renowned editors B. Cornils and W. A. Herrmann, this book presents every important aspect of aqueous-phase organometallic catalysis, a method which saves time, waste and money. The large-scale application of this "green" technology in chemical industry clearly underlines its practical use outside of academia. New chapters (for example "Organic Chemistry in Water"), 20% more content and fully updated contributions from a plethora of international authors make this book a "must-have" for everyone working in this field. From the reviews of the first edition: "This overview will be extremely useful for everyone active in this field [...]" Angewandte Chemie "This book is an essential in any chemical research library and I strongly recommend it to all synthetic research and teaching chemists. [...]" The Alchemist "The editors are to be congratulated on assembling such a wide range of contributors who have described the industrial as well as the academic aspects of the subject." [...] Journal of Organometallic Chemistry
This book is written to conclude the NATO Advanced Research Workshop "Quantum Noise in Mesoscopic Physics" held in Delft, the Netherlands, on June 2-4, 2002. The workshop was co-directed by M. Reznikov of Israel Institute of Technology, and me. The members of the organizing committee were Yaroslav Blanter (Delft), Chirstopher Glattli (Saclay and ENS Paris) and R. Schoelkopf (Yale). The workshop was very successful, and we hope that the reader will be satisfied with the scientific level of the present book. Before addressing scientific issues I find it suitable to address several non-scientific ones. The workshop was attended by researchers from many countries. Most of them perform their activities in academic institutions, where one usually finds the necessary isolation from the problems and sores of the modem world. However, there was a large group of participants for which such isolation was far from perfect. War, hatred, and violence rage just several miles away of their campuses and laboratories, poisoning everyday life in the land of Israel.
Electronic structure and physical properties of strongly correlated materials containing elements with partially filled 3d, 4d, 4f and 5f electronic shells is analyzed by Dynamical Mean-Field Theory (DMFT). DMFT is the most universal and effective tool used for the theoretical investigation of electronic states with strong correlation effects. In the present book the basics of the method are given and its application to various material classes is shown. The book is aimed at a broad readership: theoretical physicists and experimentalists studying strongly correlated systems. It also serves as a handbook for students and all those who want to be acquainted with fast developing filed of condensed matter physics.
This book covers some of the most recent advances in the field of superfluids and superconductors. More specifically, it presents some of the most advanced theoretical formulations of superfluidity and superconductivity with special regard to their topological properties and vortex dynamics together with a description of the main experiments carried out via experimental techniques at the forefront to study these two such important phenomena in condensed matter physics. Special emphasis is given to ultracold Fermi gases, to clean liquid helium and to vortex membranes and knots for the class of superfluids and to the emerging superconductivity, to intermediate states in type-I superconductors, and to heat treatments to modulate the critical temperature for the class of superconductors.
This two-volume set focuses on the chemistry and physics of engineering materials that have potential for applications in several disciplines of engineering and science. Contributions range from new methods to novel applications of existing methods. Volume 1 addresses modern analytic methodologies while Volume 2 focuses on the limitations, properties, and models of materials. The collection of topics in these volumes reflect the diversity of recent advances in chemistry and physics of engineering materials with a broad perspective that will be useful for scientists as well as for graduate students and engineers. This new two-volume set presents leading-edge research from around the world.