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Phosphorus Along the Soil-Freshwater-Ocean Continuum
Phosphorus (P) is an essential element for all organisms. However, there is a P paradox, whereby P concentrations considered deficient in some environments such as in agricultural soils are considered excessive in water, where they trigger eutrophication. Ensuring adequate P for crop production while minimizing water quality degradation requires consideration of the P continuum from soils to freshwater and oceans. It also requires an international, interdisciplinary approach to monitoring and scientific research. This eBook brings together P studies in soil science, lakes, rivers, estuaries and oceans, with 74 authors from 12 countries in Asia, Europe and North America. The papers assembled here provide important new information to address knowledge gaps, cover P forms and cycling in soil and water, and identify key priorities for future research. Thus, the papers assembled here provide current and interdisciplinary information about P forms and their cycling along the soil-freshwater-ocean continuum, which is essential for environmentally sustainable P use.
Subterranean Estuaries
Over recent decades, it has become widely recognized that water exchange between coastal aquifers and the ocean is an important component of the hydrologic cycle. Twenty years have passed since Willard S. Moore (Moore, 1999) introduced the term ‘subterranean estuary’ (STE) to identify those zones within coastal aquifers where fresh groundwater mixes with surface saltwater. Like open-water estuaries, STEs regulate the transfer of chemicals to the sea under the seashore by submarine groundwater discharge (SGD). This subterranean reactive node in the land-ocean exchange pathway has a physical, even if elusive, structure created by a combination of temporally and spatially variable mass tran...
Linking Optical and Chemical Properties of Dissolved Organic Matter in Natural Waters
A substantial increase in the number of studies using the optical properties (absorbance and fluorescence) of dissolved organic matter (DOM) as a proxy for its chemical properties in estuaries and the coastal and open ocean has occurred during the last decade. We are making progress on finding the actual chemical compounds or phenomena responsible for DOM’s optical properties. Ultrahigh resolution mass spectrometry, in particular, has made important progress in making the key connections between optics and chemistry. But serious questions remain and the last major special issue on DOM optics and chemistry occurred nearly 10 years ago. Controversies remain from the non-specific optical prop...
