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This volume deals with binary nitrogen-hydrogen compounds having two, three, or more nitrogen atoms (with the exception of hydrazine) and with compounds composed of nitrogen, hydrogen, and noble gases. The important species containing two nitrogen atoms, N2H, N2H+, N2H2, and N2H3 are described in the first part of this volume. Next, chains and cycles consisting of three nitrogen atoms are covered. Among them hydrogen azide or hydrozoic acid, HN3, is the most extensively studied nitrogen-hydrogen compound described in this volume. With increasing number of nitrogen atoms, the thermochmical stability declines. There is, however, a considerable amount of information on molecules with up to nine linked nitrogen atoms. Several of these binary nitrogen-hydrogen compounds could only be isolated in the form of organic derivatives. In that case, data available for the organic derivatives were included if they were characteristic for the particular unsubstituted N-H parent compound.
"Nitrogen" Suppt. Vol. B 1 describes the compounds of nitrogen with noble gases and, in the major part, binary compounds composed of one nitrogen atom and hydrogen. Nitrogen hydrogen compounds with two and more nitrogen atoms are covered in "Nitrogen" Suppt. Vol. 82. There is some information on various nitrogen-noble gas species, to a large extent because of the interest in their bonding behavior. Experimental data have been obtained chiefly for some singly charged cations, particularly those formed by argon Like ArN + and ArNi. The existence of others has only been established by mass spectrometry. The binary compounds of nitrogen and hydrogen comprise NH, NH , NH , NH , the corre 2 4 5 sp...
The volume is concerned exclusively with all the binary species formed between the elements silicon and fluorine such as SiF, SiF2, SiF3, SiF4, and Sif62-. Most of the volume, i.e. 144 pages, is devoted to the description of the well known physical and chemical properties of the SiF4 as well as to its preparation. This is followed in length by the report on SiF2 with its interesting chemistry, along with a section on the diatomic radical SiF. Species with fivefold and sixfold coordination of silicon are exemplified by SiF5- and by the well known SiF62-. Interestingly, the detailed models for describing the bonding situation in both ions are still a matter of discussion. While for Si2F6 most of the basic data are known, information on the chemical and physical properties of the higher members of the acylic perfluorosilanes, SinF2n+2, is scarce. All available information on the unstable cyclic perfluorosilanes of composition (SiF2)n and some even more exotic species is also included.
Published in Association with the German Historical Institute, Washington, D.C. Based on careful, intensive research in primary sources, many of these essays break new ground in our understanding of a crucial and tumultuous period. The contributors, drawn from both sides of the Atlantic, offer an in-depth analysis of how the collective memory of Nazism and the Holocaust influenced, and was influenced by, politics and culture in West Germany in the 1960s. The contributions address a wide variety of issues, including prosecution for war crimes, restitution, immigration policy, health policy, reform of the police, German relations with Israel and the United States, nuclear non-proliferation, and, of course, student politics and the New Left protest movement.