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The Bureau of Mines investigated leaching of selected copper sulfide minerals and a composite of impure flotation concentrates at elevated temperatures and pressures with ammoniacal solutions. Copper extractions of 96 percent were obtained by leaching chalcopyrite at 75° C under oxidizing conditions for 60 minutes. An extraction of 99 percent of the copper contained in the composite concentrate was obtained by leaching the product for 90 minutes at 75° C. In tests of bornite, chalcocite, and covellite, 90 to 97 percent of the copper was extracted at 20° C provided an 8-hour reaction period was used. At 75° C essentially complete dissolution of the copper from these three minerals was accomplished in 60 minutes.
This two-volume set provides a full account of hydrometallurgy. Filled with illustrations and tables, this work covers the flow of source material from the mined or concentrate state to the finished product. It also highlights ion exchange, carbon adsorption and solvent extraction processes for solution purification and concentration. The extensive reference list-over 850-makes this set a valuable resource for extraction and process metallurgists, researchers, and practitioners.
Jonathan Scragg documents his work on a very promising material suitable for use in solar cells. Copper Zinc Tin Sulfide (CZTS) is a low cost, earth-abundant material suitable for large scale deployment in photovoltaics. Jonathan pioneered and optimized a low cost route to this material involving electroplating of the three metals concerned, followed by rapid thermal processing (RTP) in sulfur vapour. His beautifully detailed RTP studies – combined with techniques such as XRD, EDX and Raman – reveal the complex relationships between composition, processing and photovoltaic performance. This exceptional thesis contributes to the development of clean, sustainable and alternative sources of energy
First Published in 1998. Routledge is an imprint of Taylor & Francis, an informa company.
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Addresses the changing definitions and approaches to corrosion occasioned by the size reductions and new materials of electronic components in devices that compete on the market to be ever smaller, faster, and functional in environments hostile to electronics (e.g. the beach). The 10 papers are from