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Marine Geology and Oceanography of the Pacific Manganese Nodule Province
Deep-sea manganese nodules, once an obscure scientific curios ity, have, in the brief span of two decades, become a potential mineral resource of major importance. Nodules that cover the sea floor of the tropical North Pacific may represent a vast ore de posit of manganese, nickel, cobalt, and copper. Modern technology has apparently surmounted the incredible problem of recovering nodules in water depths of 5000 meters and the extraction of metals from the complex chemical nodule matrix is a reality. Both the recovery and the extraction appear to be economically feasible. Exploitation of this resource is, however, hindered more by the lack of an international legal structure allowing for rec...
Cooccurrence of Fe-, Fe-Ca-, and Ca-phosphate Minerals in Concretions Within the Monterey Formation
Phosphatic concretions occur within diatomite in the upper part of the Miocene Monterey Formation near Lompoc, Calif. Absence of disruption of fine laminar bedding in the associated sediment by the concretions shows that they formed after complete compaction of the enclosing sediment. The concretions exhibit a strongly concentric color, chemical, and mineralogic zonation. Many of them are composed of a nucleus in which vivianite is the dominant mineral. Amorphous ferric phosphate, mitridatite, and francolite are the dominant phosphatic phases in successive layers toward the surface of the concretions. Cd and As contents increase tenfold from the nucleus outward, reaching a maximum of 2,000 ppm, whereas Ni content, with a maximum of 720 ppm, and Co content show the opposite trend. This mineralogy and elemental composition favor accretion under conditions of continuously increasing Eh and pH, during uplift into the fresh-ground-water zone of the terrestrial environment. Shale-normalized rare-earth-element patterns, however, suggest a marine source for the elements biogenic debris consisting of opal-A, organic matter, and carbonates of the enclosing sediment.
