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This report presents a cost analysis of Toluene Diisocyanate (TDI) production from dinitrotoluene (DNT) and chlorine. The process examined is a typical liquid-phase phosgenation process. In this process, DNT is first hydrogenated to toluenediamine (TDA) intermediate. Then, TDA reacts with phosgene in the liquid phase to produce TDI. The phosgene used is generated from chlorine and carbon monoxide in an on-site unit. Hydrogen chloride (HCl) is generated as by-product. This report was developed based essentially on the following reference(s): (1) US Patent 4185036, issued to DuPont in 1980 (2) US Patent 4193932, issued to Mitsui Toatsu in 1980 Keywords: Hydrogenation, Liquid-Phase, Phosgenation Process, Toluenediamine (TDA), Isocyanates
This report presents a cost analysis of Toluene Diisocyanate (TDI) production from dinitrotoluene (DNT) and phosgene. The process examined is a typical liquid-phase phosgenation process. In this process, DNT is first hydrogenated to toluenediamine (TDA) intermediate. Then, TDA reacts with phosgene in the liquid phase to produce TDI. Hydrogen chloride (HCl) is generated as by-product in the process. This report was developed based essentially on the following reference(s): (1) US Patent 4185036, issued to DuPont in 1980 (2) US Patent 4193932, issued to Mitsui Toatsu in 1980 Keywords: Hydrogenation, Liquid-Phase, Phosgenation Process, Toluenediamine (TDA), Isocyanates
This report presents a cost analysis of Toluene Diisocyanate (TDI) production from dinitrotoluene (DNT) and chlorine. The process examined is similar to the Bayer gas-phase phosgenation (GPP) technology. In this process, dinitrotoluene (DNT) is hydrogenated to toluenediamine (TDA). Then, TDA reacts with phosgene in gas phase to produce TDI. The phosgene used is generated from chlorine in an on-site unit. Hydrogen chloride (HCl) is generated as by-product. This report was developed based essentially on the following reference(s): (1) US Patent 9051243, issued to Bayer MaterialScience in 2015 (2) "Toluenediamine", Kirk-Othmer Encyclopedia of Chemical Technology, 5th edition Keywords: Hydrogenation, Gas-Phase, Phosgenation Process, GPP, Bayer, Isocyanates
This report presents a cost analysis of Toluene Diisocyanate (TDI) production from dinitrotoluene (DNT). The process examined is a typical reductive carbonylation process. This process is comprised of two-steps: DNT initially undergoes reductive carbonylation to form toluene dimethylcarbamate; then the carbamate is thermally decomposed to produce TDI. This report was developed based essentially on the following reference(s): (1) GB Patent 1402379, issued to Arco in 1975 (2) US Patent 4081472, issued to Mitsui Toatsu in 1984 Keywords: Non-Phosgene Process, Mitsui Toatsu, Arco
Electrochemical Sensor Analysis (ECSA) presents the recent advances in electrochemical (bio)sensors and their practical applications in real clinical, environment, food and industry related samples, as well as in the safety and security arena. In a single source, it covers the entire field of electrochemical (bio)sensor designs and characterizations. The 38 chapters are grouped in seven sections: 1) Potentiometric sensors, 2) Voltammetric sensors, 3) Electrochemical gas sensors 4) Enzyme-based sensors 5) Affinity biosensors 6) Thick and thin film biosensors and 7) Novel trends. Written by experts working in the diverse technological and scientific fields related to electrochemical sensors, each section provides an overview of a specific class of electrochemical sensors and their applications. This interdisciplinary text will be useful for researchers and professionals alike. - Covers applications and problem solving (sensitivity, interferences) in real sample analysis - Details procedures to construct and characterize electrochemical (bio)sensors
Revised by a collaborative, international, interdisciplinary team of editors and authors, this edition of the Manual of Clinical Microbiology includes the latest applications of genomics and proteomics and is filled with current findings regarding infectious agents, leading-edge diagnostic methods, laboratory practices, and safety guidelines. This edition also features four new chapters: Diagnostic Stewardship in Clinical Microbiology; Salmonella; Escherichia and Shigella; and Morganellaceae, Erwiniaceae, Hafniaceae, and Selected Enterobacterales. This seminal reference of microbiology continues to set the standard for state-of-the-science laboratory practice as the most authoritative reference in the field of microbiology. If you are looking for online access to the latest from this reference or site access for your lab, please visit www.wiley.com/learn/clinmicronow.
1. Introduction, 2. Studies on Current Transformer, 3. Studies on Capacitive Voltage Transformer, 4. Data on Electrical System
Managing sites contaminated with munitions constituents is an international challenge. Although the choice of approach and the use of Ecological Risk Assessment (ERA) tools may vary from country to country, the assurance of quality and the direction of ecotoxicological research are universally recognized as shared concerns. Drawing on a multidiscip