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Mechanisms In Heterogeneous Catalysis
Heterogeneous catalysis has developed over the past two centuries as a technology driven by the needs of society, and is part of Nobel Prize-winning science. This book describes the spectacular increase in molecular understanding of heterogenous catalytic reactions in important industrial processes. Reaction mechanism and kinetics are discussed with a unique focus on their relation with the inorganic chemistry of the catalyst material. An introductory chapter presents the development of catalysis science and catalyst discovery from a historical perspective. Five chapters that form the thrust of the book are organized by type of reaction, reactivity principles, and mechanistic theories, which provide the scientific basis to structure-function relationships of catalyst performance. Present-day challenges to catalysis are sketched in a final chapter. Written by one of the world's leading experts on the topic, this definitive text is an essential reference for students, researchers and engineers working in this multibillion-dollar field.
Ask No Questions
Some secrets were meant to stay hidden... Trust no-one After an operation goes badly wrong, undercover specialist Detective Caelan Small leaves the Metropolitan Police for good. Or so she thinks. Then the criminal responsible is seen back in the UK. Soon Caelan is drawn back into a dangerous investigation. But when the main lead is suddenly murdered, all bets are off. Nothing is as it seems. Everyone is a suspect - even close colleagues. Someone in the Met is involved and Caelan is being told to Ask No Questions. That isn't an option: Caelan needs answers... whatever the cost. The nerve-shredding new crime thriller from bestseller Lisa Hartley starts a must-read new series. Perfect for fans of Angela Marsons and Robert Bryndza, it will keep you guessing until the very end. The Detective Caelan Small Series 1. Ask No Questions 2. Tell No Lies 3. Time To Go
Photoorganocatalysis In Organic Synthesis
The use of organocatalysts able to photocatalyze an organic reaction is a rapidly growing field. These photocatalyzed transformations are more environmentally sustainable with respect to the use of expensive/toxic metal-based (photo)catalysts.Based on the authors' extensive experience in photogenerated intermediates, this book presents an overview on photocatalyzed organic processes having a synthetic significance, where an organic molecule functions as the photocatalyst.After a brief introduction defining the nature and the characteristics of a photoorganocatalyst (POC), the chapters are organized according to the class of POC used, as detailed below.Each chapter begins with a summary of the photophysical characteristics of the POCs and is followed by selected examples of synthetic applications. The last two chapters are devoted to the adoption of photoorganocatalysis in polymerization and to flow photoorganocatalysis. These in-depth explanations and practical applications make this title an essential reading for any chemistry student interested in organic (sustainable) synthesis.
Applications Of X-ray Photoelectron Spectroscopy To Catalytic Studies: From Routine Analysis To Cutting-edge Surface Characterization
X-ray photoelectron spectroscopy (XPS) has become a standard practice technique, and automated XPS facilities can be found in industry and in universities all over the world. This transformed XPS from an advanced characterization method for dedicated research, to a rather standard analysis technique of surface analysis. The catalyst's surface state is probably the most prominent factor that influences the catalytic performance. It is therefore no surprise that XPS has become an indispensable tool in studies of solid catalysts. It has been directly used to investigate issues such as the surface composition of the active catalyst and reaction and deactivation mechanisms.The objective of this b...
