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This volume contains all of the papers presented at the American Chemical Society Symposium on Reflectance Spectroscopy. The Symposium was presented under the sponsorship of the Division of Analytical Chemistry, and was held on September 11 and 12,1967, at the 154th National Meeting of the American Chemical Society, Chicago, Illinois. The papers presented herein represent a renaissance of interest in reflectance spectroscopy. The techni~ue of reflec tance spectroscopy is not, of course, a new techni~ue, however, it has only been applied to problems of a chemical interest in the last decade or so. The instrumentation for this techni~ue in the ultraviolet, visible, and near infrared regions of...
Physical Chemistry: An Advanced Treatise, Volume IV: Molecular Properties provides the aspects of the properties of single molecules and physical methods available for their determination. This book discusses linear polyatomic molecules, quantum-mechanical theory of vibrations, spectra of organic molecules, production and detection of free radicals, and force constants and molecular structure. The Hund's coupling cases for diatomic molecules, methods of measuring dipole moments, NMR spectra, and ESR spectra of organic species are also elaborated. This publication likewise covers the applications of the Mössbauer effect, electric deflection experiments, and effects of intramolecular motions on diffraction patterns. This volume is intended for graduate and physical chemistry students interested in molecular properties.
Physical Chemistry: An Advanced Treatise, Volume I: Thermodynamics deals with the applications of thermodynamics to mixtures, fluids, and solid systems at high pressures and temperatures, critical phenomena, practical handling of coupled gas equilibriums, and matter in electric, magnetic, and gravitational fields. This book begins with a survey of basic laws, followed by discussions on questions of stability, irreversible processes, surfaces, the third law, and a short introduction to Caratheodory's axiomatic foundation. The zeroth law of thermodynamics, gaseous mixtures, internal equilibrium in solids, thermodynamic properties of the mixture, and theory of linear differential forms are also elaborated. This publication presents a comprehensive treatment of physical chemistry for advanced students and researchers.
Physical Chemistry: An Advanced Treatise, Volume VIA: Kinetics of Gas Reactions discusses single reaction steps, such as transformations of atoms and molecules in specified velocities, impact parameters, and inner states into products of specified states. This book is divided into six chapters. Chapter 1 covers formal kinetics, while Chapter 2 reviews the survey of kinetic theory, as one of the bases of reaction kinetics. The Born-Oppenheimer adiabatic approximation, valence bond method, and orbital symmetry in reaction kinetics are elaborated in Chapter 3. Chapter 4 is devoted to the theory of energy transfer in molecular collisions, considering the several possible types of energy exchange. Chapter 5 focuses on the molecular beam scattering experiments on elastic, inelastic, and reactive collisions. The dynamics of bimolecular reactions are elaborated in the last chapter. This volume is intended for graduate and physical chemistry students interested in kinetics of gas reactions.
Physical Chemistry: An Advanced Treatise: Kinetics of Gas Reactions, Volume VIB, is devoted to gas phase chemical reactions. The purpose of this treatise is to present a comprehensive treatment of physical chemistry for advanced students and investigators in a reasonably small number of volumes. An attempt has been made to include all important topics in physical chemistry together with borderline subjects which are of particular interest and importance. The book contains six chapters and begins with a study on the elastic and inelastic scattering of ions on molecules, including such topics as rainbow scattering, reactive scattering, and experimental procedures and results of high-resolution...