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Thermodynamics
"The book will undoubtedly resume its place as a constant guide and reference for chemists using thermodynamics in their research, and as a textbook and reference for classes in the application of thermodynamics to chemistry." -- The Journal of Chemical Education Since its first publication in 1923, this volume has been considered one of the great books in the literature of chemistry. In the early 60s, two well-known chemists revised and updated it, adding substantial material on solution thermodynamics, results in statistical mechanics, surfaces, gravitational and electromagnetic fields, and other areas. The republication of this foundational work will be welcomed by teachers in the field.
In Memoriam
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Thermodynamics and the Free Energy of Chemical Substances
The scope of thermodynamics. Definitions; the concept of equilibrium. Conventions and mathematical methods. Solutions. The first law of thermodynamics and the concept of energy. The fugacity. Application of the second law to solutions. The perfect solution. The laws of the dilute solution. Systems involving variables other than pressure, temperature and composition. A useful function, called the activity, and its application to solutions. Change of activity with the temperature, and the calculation of activity from freezing points. The standard change of free energy; the equilibrium constant. Solutions of electrolytes. The activity of strong electrolytes. The activity of electrolytes from fr...
Thermodynamics and the Free Energy of Chemical Substances
The scope of thermodynamics. Definitions; the concept of equilibrium. Conventions and mathematical methods. Solutions. The first law of thermodynamics and the concept of energy. The fugacity. Application of the second law to solutions. The perfect solution. The laws of the dilute solution. Systems involving variables other than pressure, temperature and composition. A useful function, called the activity, and its application to solutions. Change of activity with the temperature, and the calculation of activity from freezing points. The standard change of free energy; the equilibrium constant. Solutions of electrolytes. The activity of strong electrolytes. The activity of electrolytes from fr...
