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Solvent-Free Methods in Nanocatalysis Discover solvent-free approaches for the synthesis of nanocatalysts as well as various catalytic transformations in this unique one-stop resource Solvent-free methods have attracted wide attention in organic synthesis and catalysis as a promising approach towards “greener” and more sustainable chemical transformations. In this regard, nanocatalysis has seen particular growth in recent years. Solvent-Free Methods in Nanocatalysis gives an in-depth overview of nanocatalysts and their catalytic applications using solvent-free methods. After a brief introduction, it covers various synthetic techniques for the preparation of nanocatalysts and supports usi...
The continuous effort to perform a more sustainable chemistry has led to the development of new materials that accomplish the principles of green chemistry. In this context, deep eutectic solvents (DESs) have arisen as a new generation of solvents that respond well to most of the characteristics that an ideal green solvent must possess: they are easy and cheap to prepare, stable, easy to handle (they show chemical stability, non-flammability and conductivity), separable from the reaction products, biodegradable and safe for both humans and the environment. At the same time, they show chemical-physical properties similar to ionic liquids, such as low volatility, conductivity and high solvent ...
Carbon-carbon and carbon-heteroatom bond-forming reactions are the backbone of synthetic organic chemistry. Scientists are constantly developing and improving these techniques in order to maximize the diversity of synthetically available molecules. These techniques must be developed in a sustainable manner in order to limit their environmental impact. This book highlights green carbon-carbon and carbon-heteroatom bond forming reactions.
The era of nanoscience and its technology has become increasingly important in last two decades and this encompasses a vast range of unimaginable applications for forthcoming decades. Investigators are engaged in the manipulation of materials in the nano scale for studying their properties with making the desirable devices. The range between 1-100 nm (nm = nanometer) is generally considered as a nano scale and this scale is basically useful for measurement of the dimensions (length or width or area or height) of particles or constituents or atoms or molecules, etc. At this scale, everything, regardless of what it is, has different properties to that of their bulk counterparts and these make "nano" so fascinating!
Today, there is growing interest in aqueous-phase catalytic conversions for the valorization of renewable biomass-based feedstocks for biorefineries to produce, in a sustainable way, biofuels, chemicals, power, energy, materials, pharmaceuticals and food. This is because of the highly polar nature of water which makes it an ideal medium to convert polar biomass-based lignocellulose (cellulose, hemicellulose, lignin), with high oxygen content, and their upgraded products such as hydrophilic carbohydrates, platform chemicals and their derivatives. Another reason which makes water the solvent of choice is that water itself is involved either as a reagent or as a byproduct even in large amounts ...
We are proposing this comprehensive volume aimed at bridging and bonding of the theory and practical experiences for the elimination of a broad range of pollutants from various types of water and soil utilizing innovative nanotechnologies, biotechnologies and their possible combinations. Nowadays, a broad range of contaminants are emerging from the industry (and also representing old ecological burdens). Accidents and improper wastewater treatment requires a fast, efficient and cost-effective approach. Therefore, several innovative technologies of water and soil treatments have been invented and suggested in a number of published papers. Out of these, some nanotechnologies and biotechnologie...
This book systematically introduces the fundamentals, preparation technology, state-of-the-art applications, and future development of biomass-derived porous carbon materials. The authors provide a theoretical foundation that demonstrates the microstructure and physicochemical properties of carbon materials. The fabrication methods, including physical activation methods, chemical activation methods, and advances in other new fabrication methods are explicitly described. The book also identifies many potential applications of biomass (especially biomass-derived porous carbon materials), such as supercapacitors, removal of organic pollutants from water, CO2 capture, photocatalytic application, and farmland restoration. The book will be a valuable resource for researchers, scientists, and engineers working in the field of biomass-derived porous carbon materials, carbon resource development, and environmental protection.
The valorization of lignocellulosic biomass, in the form of forest and agricultural wastes, industrial processing side-streams, and dedicated energy crops, toward chemicals, fuels and added-value products has become a major research area with increasing exploitation potential. The efficient and tailored depolymerization of biomass or its primary structural components (hemicellulose, cellulose, and lignin) to platform chemicals, i.e., sugars, phenolics, furans, ketones, organic acids, etc. is highly dependent on the development of novel or modified chemo- and bio-catalytic processes that take into account the peculiarities and recalcitrance of biomass as feedstock, compared for example to pet...
Surface Modified Nanomaterials for Applications in Catalysis: Fundamentals, Methods and Applications provides an overview of the different state-of-the-art surface modification methods of nanomaterials and their commercial applications. The main objective of this book is to comprehensively cover the modification of nanomaterial and their fabrication, including different techniques and discussions of present and emerging commercial applications. The book addresses fundamental chemistry concepts as applied to the modification of nanomaterials for applications in energy, catalysis, water remediation, sensors, and more. Characterization and fabrication methodologies are reviewed, along with the ...