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Volume 4 focuses on additions and the resulting substitutions at carbon-carbon &pgr;-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient &pgr;-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to &pgr;-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.
The two-part, fifth edition of Advanced Organic Chemistry has been substantially revised and reorganized for greater clarity. The material has been updated to reflect advances in the field since the previous edition, especially in computational chemistry. Part B describes the most general and useful synthetic reactions, organized on the basis of reaction type. It can stand-alone; together, with Part A: Structure and Mechanisms, the two volumes provide a comprehensive foundation for the study in organic chemistry. Companion websites provide digital models for students and exercise solutions for instructors.
Organized to provide maximum utility to the bench synthetic chemist. The editor is well-known for his work in exploring, developing, and applying organopalladium chemistry. Contributors include over 24 world authorities in the field.
Like its three successful predecessors, 'Organic Synthesis Highlights IV' allows an exciting yet brief survey of modern synthetic methods. More than 40 articles - short, precise and topical - give an overview of the most recent developments and trends in the field. Readers will learn about the key synthetic strategies, new effective methods in enantioselective catalysis, transition metal catalyzed reactions and stereoselective synthesis and applications for the synthesis of natural and non-natural products that are important for their daily work. Much emphasis is placed on referencing in order to make the primary literature easily accessible. Prof. H.-G. Schmalz carefully selected the contributions with a view to creating an up-to-date and critical survey of the current state of the art in organic synthesis
The continually growing contribution of transition metal chemistry to synthetic organic chemistry is, of course, widely recognized. Equally well known is the difficulty in keeping up-to-date with the multifarious reactions and procedures that seem to be spawned at an ever-increasing rate. These can certainly be summarized on the basis of reviews under the headings of the individual transition metals. More useful to the bench organic chemist, however, would be the opposite type of concordance based on the structural type of the desired synthetic product. This is the approach taken in the present monograph, which presents for each structural entity a conspectus of the transition metal-mediated...
Metal-arene p-complexes show a rich and varied chemistry. The metal adds a third dimension to the planar aromatic compounds and coordination of a metal to an arene thus not only altering the reactivity of ring-carbons and substituents but also makes possible reactions that lead to chiral non-racemic products. This book, organized in nine chapters and written by leading scientists in the field provides the reader with an up-to-date treatise on the subject organized according to reaction type and use. It covers the wide spectrum of arene activation: from the electrophilic activation of h6-bound areneï by p-Lewis acid metal complex fragments, to reactions of nucleophilic h2-coordinated aren...
Graduate Programs in the Physical Sciences, Mathematics, Agricultural Sciences, the Environment & Natural Resources 2012 contains more than 2,900 graduate programs in 59 disciplines-including agriculture and food sciences, astronomy and astrophysics, chemistry, physics, mathematics, environmental sciences and management, natural resources, marine sciences, and more. This guide is part of Peterson's six-volume Annual Guides to Graduate Study, the only annually updated reference work of its kind, provides wide-ranging information on the graduate and professional programs offered by U.S.-accredited colleges and universities in the United States and throughout the world. Informative data profile...
Peterson's Graduate Programs in the Physical Sciences, Mathematics, Agricultural Sciences, the Environment & Natural Resources contains a wealth of information on colleges and universities that offer graduate work in these exciting fields. The institutions listed include those in the United States and Canada, as well international institutions that are accredited by U.S. accrediting bodies. Up-to-date information, collected through Peterson's Annual Survey of Graduate and Professional Institutions, provides valuable information on degree offerings, professional accreditation, jointly offered degrees, part-time and evening/weekend programs, postbaccalaureate distance degrees, faculty, student...
Peterson's Graduate Programs in the Physical Sciences contains a wealth of information on colleges and universities that offer graduate work in Astronomy and Astrophysics, Chemistry, Geosciences, Marine Sciences and Oceanography, Meteorology and Atmospheric Sciences, and Physics. The institutions listed include those in the United States, Canada, and abroad that are accredited by U.S. accrediting bodies. Up-to-date information, collected through Peterson's Annual Survey of Graduate and Professional Institutions, provides valuable information on degree offerings, professional accreditation, jointly offered degrees, part-time and evening/weekend programs, postbaccalaureate distance degrees, fa...
Organonickel chemistry plays an increasingly important role in organic chemistry, and interest in this topic is now just as keen as in organopalladium chemistry. While there are numerous, very successful books on the latter, a book specializing in organonickel chemistry is long overdue. Edited by one of the leading experts in the field, this volume covers the many discoveries made over the past 30 years, and previously scattered throughout the literature. Active researchers working at the forefront of organonickel chemistry provide a comprehensive review of the topic, including cross-coupling reactions, asymmetric synthesis and heterogeneous catalysis reaction types. A must-have for both organometallic chemists and synthetic organic chemists.