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Chemical Thermodynamics of Americium
This is the second volume in a series of critical reviews of the chemical thermodynamic data of those elements of particular importance in the safety assessment modeling of high-level radioactive waste storage and disposal facilities. The objective of these reviews is to provide a set of reliable thermodynamic data that can be used to describe the behaviour of these elements under conditions relevant for radioactive waste disposal systems and the geochemical environments. The present volume is a review of experimental data reported in the literature for americium. On a few occasions, where no data existed, comparisons and estimates were made based on experimental data on analog lanthanide elements. The basic philosophy was to develop a minimum set of solid phases and solution species of americium that would fit all experimental data being reviewed.
Development and Applications in Solubility
Solubility is fundamental to most areas of chemistry and is one of the most basic of thermodynamic properties. It underlies most industrial processes. Bringing together the latest developments and ideas, Developments and Applications in Solubility covers many varied and disparate topics. The book is a collection of work from leading experts in their fields and covers the theory of solubility, modelling and simulation, industrial applications and new data and recent developments relating to solubility. Of particular interest are sections on: experimental, calculated and predicted solubilities; solubility phenomena in 'green' quaternary mixtures involving ionic liquids; molecular simulation approaches to solubility; solubility impurities in cryogenic liquids and carbon dioxide in chemical processes. The book is a definitive and comprehensive reference to what is new in solubility and is ideal for researcher scientists, industrialists and academics
High Temperature Thermodynamic Studies on the Transuranium Oxides and Their Solid Solutions
A growing demand for energy supply worldwide, coupled with the necessity to reduce emission of greenhouse gases, has led to a renewed interest in nuclear energy as an alternative to fossil fuels for electricity production in the last years. One of the ma
Reactor Dosimetry
Proceedings of the 8th ASTM-Euratom Symposium, held in Vail, Colorado, Aug.-Sept. 1993, to provide a forum for experts to discuss their latest results under the broad theme of dosimetry for the correlation of radiation effects. Preceded by a summary of the keynote presentations and followed by summa
Nagra/PSI Chemical Thermodynamic Data Base 01/01
The Nagra/PSI Chemical Thermodynamic Data Base 01/01 is an encyclopedia of thermodynamic data recommended for environmental studies. The data base focuses on elements commonly found as major solutes in natural waters, and on actinides and fission products relevant for radioactive waste disposal projects. It is the official chemical thermodynamic data base used in Swiss radioactive waste disposal projects. The detailed discussion of every number recommended in this encyclopedia is the result of a multi man-year project of the Paul Scherrer Institut (PSI), a Swiss National Lab. The five authors of this work have many years of experience in research, data base development and the application of...
The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5)
The Chemistry of the Actinide and Transactinide Elements is a contemporary and definitive compilation of chemical properties of all of the actinide elements, especially of the technologically important elements uranium and plutonium, as well as the transactinide elements. In addition to the comprehensive treatment of the chemical properties of each element, ion, and compound from atomic number 89 (actinium) through to 109 (meitnerium), this multi-volume work has specialized and definitive chapters on electronic theory, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic properties, the metals, coordination chemistry, ...
Solvent Extraction Principles and Practice, Revised and Expanded
A complete and up-to-date presentation of the fundamental theoretical principles and many applications of solvent extraction, this enhanced Solvent Extraction Principles and Practice, Second Edition includes new coverage of the recent developments in solvent extraction processes, the use of solvent extraction in analytical applications and waste recovery, and computational chemistry methods for modeling the solvent extraction of metal ions. Offering sound scientific and technical descriptions in a format accessible to students and expedient for researchers and engineers, this edition also features a new chapter on ionic strength corrections and contains more than 850 up-to-date literature citations.
The Chemistry of the Actinide and Transactinide Elements (Set Vol.1-6)
The fourth edition of "The Chemistry of the Actinide and Transactinide Elements" comprises all chapters in volumes 1 through 5 of the third edition (published in 2006) plus a new volume 6. To remain consistent with the plan of the first edition, “ ... to provide a comprehensive and uniform treatment of the chemistry of the actinide [and transactinide] elements for both the nuclear technologist and the inorganic and physical chemist,” and to be consistent with the maturity of the field, the fourth edition is organized in three parts. The first group of chapters follows the format of the first and second editions with chapters on individual elements or groups of elements that describe and ...
Chemical Thermodynamics of Selenium
In order to quantitatively predict the chemical reactions that hazardous materials may undergo in the environment, it is necessary to know the relative stabilities of the compounds and complexes that may be found under certain conditions. This type of calculations may be done using consistent chemical thermodynamic data, such as those contained in this book for inorganic compounds and complexes of selenium.* Fully detailed authoritative critical review of literature.* Integrated into a comprehensive and consistent database for waste management applications.* CD ROM version.
