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Understanding Voltammetry
Considers how to go about designing, explaining and interpreting experiments centered around various forms of voltammetry (cyclic, microelectrode, hydrodynamic, and so on). This book gives introductions to the theories of electron transfer and of diffusion. It also introduces convection and describes hydrodynamic electrodes.
Electrode Potentials
Another winning primer! This new addition to the popular series provides a basic introduction to equilibrium electrochemistry, focusing on electrode potentials and their applications. It builds on a knowledge of elementary thermodynamics giving the student an appreciation of the origin of electrode potentials and shows how these are used to deduce a wealth of chemically important information and data such as equilibrium constants, the free energy, enthalpy and entropy changes of chemical reactions, activity coefficients, the selective sensing of ions. It is mathematically simple, the emphasis throughout is on understanding the foundations of the subject and how it may be used to study problems of chemical interest.
Understanding Voltammetry
Preface to the second edition -- Preface to the first edition - Introduction -- Mathematical model of an electrochemical system -- Numerical solution of the model system -- Diffusion-only electrochemical problems in one-dimensional systems -- First-order chemical kinetic mechanisms -- Second-order chemical kinetic mechanisms -- Electrochemical simulation in weakly supported media -- Hydrodynamic voltammetry -- Two-dimensional systems: microdisc electrodes -- Heterogeneous surfaces -- Stochastic electrochemistry.
Understanding Voltammetry
he power of electrochemical measurements in respect of thermodynamics, kinetics and analysis is widely recognised but the subject can be unpredictable to the novice even if they have a strong physical and chemical background, especially if they wish to pursue quantitative measurements. Accordingly, some significant experiments are perhaps wisely never attempted while the literature is sadly replete with flawed attempts at rigorous voltammetry. This textbook considers how to implement designing, explaining and interpreting experiments centered on various forms of voltammetry (cyclic, microelectrode, hydrodynamic, etc.). The reader is assumed to have knowledge of physical chemistry equivalent to Master's level but no exposure to electrochemistry in general, or voltammetry in particular. While the book is designed to stand alone, references to important research papers are given to provide an introductory entry into the literature. The third edition contains new material relating to electron transfer theory, experimental requirements, scanning electrochemical microscopy, adsorption, electroanalysis and nanoelectrochemistry.
Electrochemistry
Reflecting the growing volume of published work in this field, researchers will find this book an invaluable source of information on current methods and applications.
Electrochemical Strategies in Detection Science
Electrochemical methods of chemical analysis have been widely used for many years, the purpose of this volume is to address research and development advances based on new and re-vitalised methods, new materials with enhanced properties and new devices that achieve better electroanalytical signal generation.
Electrode Kinetics: Principles and Methodology
Volumes 26 and 27 are both concerned with reactions occurring at electrodes arising through the passage of current. They provide a comprehensive review of the study of electrode kinetics. The basic ideas and experimental methodology are presented in Volume 26 whilst Volume 27 deals with reactions at particular types of electrodes.Chapter 1 serves as an introduction to both volumes and is a survey of the fundamental principles of electrode kinetics. Chapter 2 deals with mass transport - how material gets to and from an electrode. Chapter 3 provides a review of linear sweep and cyclic voltammetry which constitutes an extensively used experimental technique in the field. Chapter 4 discusses a.c. and pulse methods which are a rich source of electrochemical information. Finally, chapter 5 discusses the use of electrodes in which there is forced convection, the so-called ``hydrodynamic electrodes''.
A. G. Stromberg - First Class Scientist, Second Class Citizen: Letters From The Gulag And A History Of Electroanalysis In The Ussr
Armin G Stromberg was arguably one of the founding fathers of the technique of stripping voltammetry frequently used in chemical analysis, yet he is virtually unheard of in Western scientific circles. He was a brilliant scientist, but due to his German ancestry he was interred in one of the NKVD GULAG camps at the outbreak of the Second World War.This semi-biographical history presents the complete set of 74 surviving letters written by Stromberg to his wife during this period. The letters provide both historians and the interested public with a rare and unique glimpse into the everyday living conditions of inmates in one of the GULAG labour camps. The book also traces Stromberg's life follo...
Applications of Kinetic Modelling
Volume 37 is concerned with the use and role of modelling in chemical kinetics and seeks to show the interplay of theory or simulation with experiment in a diversity of physico-chemical areas in which kinetics measurements provide significant physical insight. Areas of application covered within the volume include electro- and interfacial chemistry, physiology, biochemistry, solid state chemistry and chemical engineering. A leading contributor to this general area has been Professor W. John Albery, FRS, to whom the contributors and editors dedicate this book.
Research in Chemical Kinetics
This series of volumes aims to publish authoritative review articles on a wide range of exciting and contemporary topics in gas and condensed phase kinetics. Research in Chemical Kinetics complements the acclaimed series Comprehensive Chemical Kinetics, and is edited by the same team of professionals. The reviews contained in this volume are concise, topical accounts of specific research written by acknowledged experts. The authors summarize their latest work and place it in a general context. Particular strengths of the volume are the quality of the contributions and their topicality, and the rapid publication realized.
