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The derivation of structural information from spectroscopic data is now an integral part of organic chemistry courses at all Universities. A critical part of any such course is a suitable set of problems to develop the student’s understanding of how structures are determined from spectra. Organic Structures from Spectra, Fifth Edition is a carefully chosen set of more than 280 structural problems employing the major modern spectroscopic techniques, a selection of 27 problems using 2D-NMR spectroscopy, more than 20 problems specifically dealing with the interpretation of spin-spin coupling in proton NMR spectra and 8 problems based on the quantitative analysis of mixtures using proton and c...
The well-known historian and political scientist Zeev Sternhell here advances a radically new interpretation of the founding of modern Israel. The founders claimed that they intended to create both a landed state for the Jewish people and a socialist society. However, according to Sternhell, socialism served the leaders of the influential labor movement more as a rhetorical resource for the legitimation of the national project of establishing a Jewish state than as a blueprint for a just society. In this thought-provoking book, Sternhell demonstrates how socialist principles were consistently subverted in practice by the nationalist goals to which socialist Zionism was committed. Sternhell e...
Applications of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry, Second Edition focuses on the applications of nuclear magnetic resonance spectroscopy to problems in organic chemistry and the theories involved in this kind of spectroscopy. The book first discusses the theory of nuclear magnetic resonance, including dynamic and magnetic properties of atomic nuclei, nuclear resonance, and relaxation process. The manuscript also examines the experimental method. Topics include experimental factors that influence resolution and the shapes of absorption lines; measurement of line posit...
The Civil War thrust millions of men and women—rich and poor, soldiers and civilians, enslaved and free—onto the roads of the South. During four years of war, Southerners lived on the move. In the hands of Sternhell, movement becomes a radically new means to perceive the full trajectory of the Confederacy’s rise, struggle, and ultimate defeat.
In this masterful work of historical scholarship, Zeev Sternhell, an internationally renowned Israeli political scientist and historian, presents a controversial new view of the fall of democracy and the rise of radical nationalism in the twentieth century. Sternhell locates their origins in the eighteenth century with the advent of the Anti-Enlightenment, far earlier than most historians. The thinkers belonging to the Anti-Enlightenment (a movement originally identified by Friederich Nietzsche) represent a perspective that is antirational and that rejects the principles of natural law and the rights of man. Sternhell asserts that the Anti-Enlightenment was a development separate from the Enlightenment and sees the two traditions as evolving parallel to one another over time. He contends that J. G. Herder and Edmund Burke are among the real founders of the Anti-Enlightenment and shows how that school undermined the very foundations of modern liberalism, finally contributing to the development of fascism that culminated in the European catastrophes of the twentieth century.
"Few books on European history in recent memory have caused such controversy and commotion," wrote Robert Wohl in 1991 in a major review of Neither Right nor Left. Listed by Le Monde as one of the forty most important books published in France during the 1980s, this explosive work asserts that fascism was an important part of the mainstream of European history, not just a temporary development in Germany and Italy but a significant aspect of French culture as well. Neither right nor left, fascism united antibourgeois, antiliberal nationalism, and revolutionary syndicalist thought, each of which joined in reflecting the political culture inherited from eighteenth-century France. From the first, Sternhell's argument generated strong feelings among people who wished to forget the Vichy years, and his themes drew enormous public attention in 1994, as Paul Touvier was condemned for crimes against humanity and a new biography probed President Mitterand's Vichy connections. The author's new preface speaks to the debates of 1994 and reinforces the necessity of acknowledging the past, as President Chirac has recently done on France's behalf.
Offers a realistic approach to solving problems used by organic chemists. Covering all the major spectroscopic techniques, it provides a graded set of problems that develop and consolidate students' understanding of organic spectroscopy. This edition contains more elementary problems and a modern approach to NMR spectra.
When The Birth of Fascist Ideology was first published in 1989 in France and at the beginning of 1993 in Italy, it aroused a storm of response, positive and negative, to Zeev Sternhell's controversial interpretations. In Sternhell's view, fascism was much more than an episode in the history of Italy. He argues here that it possessed a coherent ideology with deep roots in European civilization. Long before fascism became a political force, he maintains, it was a major cultural phenomenon. This important book further asserts that although fascist ideology was grounded in a revolt against the Enlightenment, it was not a reactionary movement. It represented, instead, an ideological alternative t...
This is the fourth set of Handbook of Porphyrin Science.Porphyrins, phthalocyanines and their numerous analogues and derivatives are materials of tremendous importance in chemistry, materials science, physics, biology and medicine. They are the red color in blood (heme) and the green in leaves (chlorophyll); they are also excellent ligands that can coordinate with almost every metal in the Periodic Table. Grounded in natural systems, porphyrins are incredibly versatile and can be modified in many ways; each new modification yields derivatives, demonstrating new chemistry, physics and biology, with a vast array of medicinal and technical applications.As porphyrins are currently employed as pl...
Dynamic Nuclear Magnetic Resonance Spectroscopy provides an overview of the state of knowledge in dynamic nuclear magnetic resonance (DNMR) spectroscopy. The early chapters describe the theoretical basis and practical techniques which have or will be used for extracting kinetic data from DNMR spectra. The subsequent chapters provide reviews of the many areas in which DNMR spectroscopy has been applied. Key topics covered include nuclear exchange processes; band-shape analysis; application of nonselective pulsed NMR experiments: diffusion and chemical exchange; spin-spin relaxation time determination; rotation about single and double bonds in organic molecules; and dynamic molecular processes in inorganic and organometallic compounds. Also discussed are studies on stereochemical nonrigidity in organometallic and metal carbonyl compounds; fluxional allyl complexes; carbonium ion rearrangements; and proton transfer processes. It is hoped that this volume will provide a literature guide, source book, and progress report which will be helpful to all those who will continue or will begin work in this field.