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An up-to-date and two volume overview of recent developments in the field of chemocatalytic and enzymatic processes for the transformation of renewable material into essential chemicals and fuels. Experts from both academia and industry discuss catalytic processes currently under development as well as those already in commercial use for the production of bio-fuels and bio-based commodity chemicals. As such, they cover drop-in commodity chemicals and fuels, as well as bio-based monomers and polymers, such as acrylic acid, glycols, polyesters and polyolefins. In addition, they also describe reactions applied to waste and biomass valorization and integrated biorefining strategies. With its comprehensive coverage of the topic, this is an indispensable reference for chemists working in the field of catalysis, industrial chemistry, sustainable chemistry, and polymer synthesis.
The objective of this Special Issue is to provide new contributions in the area of biomass valorization using heterogeneous catalysts and focusing specifically on the structure/activity relationships of specific and important oxidation, hydrogenation, hydrodeoxygenation and biocatalytic processes. The issue emphasizes the influence of the design and morphology of the catalyst, in terms of particle size, redox and acid-base properties and catalyst stability. Finally, mechanistic studies and examples of design and optimization of industrial processes are presented.
In the last decades, inedible lignocellulosic biomasses have attracted significant attention for being abundant resources that are not in competition with agricultural land or food production and, therefore, can be used as starting renewable material for the production of a wide variety of platform chemicals. The three main components of lignocellulosic biomasses are cellulose, hemicellulose and lignin, complex biopolymers that can be converted into a pool of platform molecules including sugars, polyols, alchols, ketons, ethers, acids and aromatics. Various technologies have been explored for their one-pot conversion into chemicals, fuels and materials. However, in order to develop new catalytic processes for the selective production of desired products, a complete understanding of the molecular aspects of the basic chemistry and reactivity of biomass derived molecules is still crucial. This Special Issue reports on recent progress and advances in the catalytic valorization of cellulose, hemicellulose and lignin model molecules promoted by novel heterogeneous systems for the production of energy, fuels and chemicals.
Diminishing confined fossil resources has spurred the scientific community to strive for alternative, sustainable resources, such as terrestrial biomass, which can potentially substitute fossil-based derivatives. Lignocellulosic biomass is deemed an indispensable carbon source for meeting industrial and social demands regarding energy/fuels and chemicals. Over the past decade, significant advances have been shown in developing a broad spectrum of high-value chemicals and functional materials derived from biomass-based substrates. In connection with this, furanic chemicals, such as 5-hydroxymethylfurfural (HMF) and furfural, have recently received considerable attention due to their potential...
Horizons in Sustainable Industrial Chemistry and Catalysis, Volume 178, presents a comprehensive picture of recent developments in terms of sustainable industrial processes and the catalytic needs and opportunities to develop these novel routes. Each chapter includes an introduction and state-of-the-art in the field, along with a series of specific aspects and examples. The book identifies new opportunities for research that will help us transition to low carbon and sustainable energy and chemical production. Users will find an integrated view of the new possibilities in this area that unleashes new possibilities in energy and chemistry. - Combines an analysis of each scenario, the state-of-the art, and specific examples to help users better understand needs, opportunities, gaps and challenges - Offers an integrated view of new catalytic technologies that are needed for future use - Presents an interdisciplinary approach that combines broad expertise - Brings together experts in the area of sustainable industrial chemistry
This book provides state-of-the-art reviews, current research, prospects and challenges of the production of biofuels and chemicals such as furanic biofuels, biodiesel, carboxylic acids, polyols and others from lignocellulosic biomass, furfurals, syngas and γ-valerolactone with bifunctional catalysts, including catalytic, and combined biological and chemical catalysis processes. The bifunctionality of catalytic materials is a concept of not only using multifunctional solid materials as activators, but also design of materials in such a way that the catalytic materials have synergistic characteristics that promote a cascade of transformations with performance beyond that of mixed mono-functional catalysts. This book is a reference designed for researchers, academicians and industrialists in the area of catalysis, energy, chemical engineering and biomass conversion. Readers will find the wealth of information contained in chapters both useful and essential, for assessing the production and application of various biofuels and chemicals by chemical catalysis and biological techniques.
This book deals with the search for environmentally benign procedures for the oxidation of alcohols and gives an overview of their transition-metal-catalyzed aerobic oxidation.
This book highlights theoretical and experimental facts about selective nano-metal oxides. TiO2 ,ZnO and transition metal oxides which are known to be semiconductors and find applications in various fields. This book presents about recent findings like photo catalysis, sensing ,coating and biomedical applications. Therapeutic and future applications that are recently been reported of various metal oxides are presented in this book.
The environment is an all-encompassing component of the ecosystem of "Blue planet - the earth", made up of the hydrosphere, atmosphere and lithosphere. These three spheres have biotic and abiotic components which exhibit ecological homeostasis that provides the most appropriate survival chances for the members of biotic component and geochemical balance with abiotic components. This ecosystem is subjected to relatively harsh conditions, mostly created by the disastrous activities due to natural calamities and intentional and/or accidental anthropogenic activities. Biotechnology has become a potential tool to dissipate such environmental impacts because of the advancement it has undergone rec...