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The generally accepted definitions of acids and bases together with the generalized definition for the solvent system introduced by the author for the description of both molecular and ionic solvents are discussed. The oxobasicity index introduced as a measure of relative oxoacidic properties of ionic melts (pIL) and methods of its determination are presented. Moreover, the oxoacidity scales of ionic melts based on alkali metal halides at different temperatures are constructed. The sequential addition method (SAM), proposed by the author to investigate the effect of oxide particle size on oxide solubilities is presented. This book is meant for specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena. It will also be useful for those chemists who wish to extend their knowledge of physical and solution chemistry. - First book devoted to oxoacids and oxobases - Aimed at specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena - The perfect handbook for beginners looking for preliminary knowledge about methods of investigation
This 4th edition of Handbook of Solvents, Volume 1, contains the most recent findings and trends in solvent applications. It is a comprehensive survey of the science of solvents and their properties, covering all aspects of solvent behavior that are relevant to their use in chemical and related industries including agricultural and technical processes, inorganic synthesis and materials chemistry, and more. Divided into two volumes, this first volume covers high-level information on the physical chemical properties of the most relevant solvent systems. Each chapter is focused on a specific aspect of solvent properties that determine its selection, such as the effect on properties of solutes a...
Authorship Attribution surveys the history and present state of the discipline, presenting some comparative results where available. It also provides a theoretical and empirically-tested basis for further work. Many modern techniques are described and evaluated, along with some insights for application for novices and experts alike.
A comprehensive, extensive textual analysis of the principles of solvent selection and use, the handbook is intended to help formulators select ideal solvents, safety coordinators to protect workers, and legislators and inspectors to define and implement technically correct public safeguards for use, handling, and disposal.
Petroleum Engineer's Guide to Oil Field Chemicals and Fluids is a comprehensive manual that provides end users with information about oil field chemicals, such as drilling muds, corrosion and scale inhibitors, gelling agents and bacterial control. This book is an extension and update of Oil Field Chemicals published in 2003, and it presents a compilation of materials from literature and patents, arranged according to applications and the way a typical job is practiced. The text is composed of 23 chapters that cover oil field chemicals arranged according to their use. Each chapter follows a uniform template, starting with a brief overview of the chemical followed by reviews, monomers, polymer...
The emerging field of green analytical chemistry is concerned with the development of analytical procedures that minimize consumption of hazardous reagents and solvents, and maximize safety for operators and the environment. In recent years there have been significant developments in methodological and technological tools to prevent and reduce the deleterious effects of analytical activities; key strategies include recycling, replacement, reduction and detoxification of reagents and solvents. The Handbook of Green Analytical Chemistry provides a comprehensive overview of the present state and recent developments in green chemical analysis. A series of detailed chapters, written by internatio...
During the last few years, carbonatites have received a considerable amount of attention. Some of this interest was no doubt kindled by the importance of volatiles in the Earth's mantle, particularly CO , by the fact that carbonatites 2 can be used to monitor the chemical evolution of the sub-continental upper mantle, and by the fact that carbonatites may be effective metasomatizing agents at both mantle and crustal levels. The interest in Oldoinyo Lengai has extended over at least 100 years, but it was not until the eruptions of 1960, when the unique carbonatitic nature of its lavas was recognized, that the volcano took on special significance in volcanology and igneous petrology. The recognition of carbonatitic flows coin cided with the first successful laboratory experiments carried out on carbonatitic melts. Since then, Oldoinyo Lengai has formed a cornerstone in all carbonatite discussions. It is probably true to say that the findings from Oldoinyo Lengai have dominated our ideas about carbonatites, in spite of the fact that the alkali rich, natrocarbonatitic lavas of Oldoinyo Lengai are markedly different from other carbonatites.
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