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Aromatic Organic Chemistry
This book is written for B.Sc. (Hons.) and M.Sc. students of various universities. In this book my aim has been describe the fundamental principles of organic chemistry. Since I do not consider the chemistry of natural products to be fundamental chemistry but rather the application of fundamental principles. The subject matter described in this book covers much of the basic organic chemistry that is needed by a student who which to study chemistry as a main subject at degree level. The arrangement of the subject-matter is based on homologous series and in general, descriptions of reactions are followed by discussion of their mechanisms and these includes an elementary account of the sort of evidence that led workers to suggest mechanisms that are acceptable at the present time.
Aromatic Chemistry
All the basic principles of this important topic are clearly presented here in an account which takes as examples many compounds of industrial and biological significance. Consideration is given to the structure, reactions, and properties of benzene and classes of aromatic compounds derived from it, and topics such as thermodynamic versus kinetic control and pericyclic reactions are introduced. The text also covers polycyclic arenes and the small and large ring systems which are embraced by the wider definition of aromaticity.
Aromatic Compounds
Second Supplements to the 2nd Edition of Rodd's Chemistry of Carbon Compounds, Volume III: Aromatic Compounds spans several very important areas of aromatic chemistry. It contains five chapters (Chapters 8-12) devoted to benzoquinone, nitro compounds, metallo derivatives, and aromatic hydrocarbons. The book begins with a chapter containing literature on benzoquinones and related compounds published from the 1970s to mid-1994. Subsequent chapters cover materials on derivatives of benzenoid hydrocarbons with substituents containing a single nitrogen atom; aromatic compounds of the non-transition metals; aromatic compounds of the transition elements; and nuclear substituted benzenoid hydrocarbons with more than one nitrogen atom in the substituent.
The Structures & Reactions of the Aromatic Compounds
The benzene problem. The theoretical solution of the benzene problem and a definition of the term aromatic. Some properties of arotic compounds. Addition reactions of aromatic compounds. The aromatic double bond. The effects of substituents. Aromatic substitution reations. The diels alder reaction. Photo-oxidation and photo-dimerization. Absorption and fluorescence spectra of aromatica compounds. Optical activity in aromatic compounds.
Synthesis of Aromatic Compounds
Aromatic compounds are a diverse and fascinating class of compounds with wide-ranging importance. This book provides an overview of the synthesis and reactivity of aromatic compounds. The publication covers the many important reaction types, such as electrophilic and nucleophilic substitution, the reactivity of benzynes, aryllithium chemistry, and transition metal-mediated reactions. It also includes a discussion of the synthesis of heteroaromatic compounds, polycyclic aromatic compounds, and nonplanar aromatic systems. This book focusses on reaction mechanisms and numerous examples of applications in multistep synthesis of aromatic compounds.
Arene Chemistry
Organized to enable students and synthetic chemists to understand and expand on aromatic reactions covered in foundation courses, the book offers a thorough and accessible mechanistic explanation of aromatic reactions involving arene compounds. • Surveys methods used for preparing arene compounds and their transformations • Connects reactivity and methodology with mechanism • Helps readers apply aromatic reactions in a practical context by designing syntheses • Provides essential information about techniques used to determine reaction mechanisms
Aromatic Chemistry
This book provides material required by undergraduate students and is also ideal for industrial chemists seeking to update their knowledge of this important aspect of chemistry.
Birch Reduction of Aromatic Compounds
Birch reduction (see reviews [1-5]) is the name given to the reaction of unsaturated organic compounds with alkali metals and alcohols in liquid am monia. This method was first used for aromatic compounds in 1937 by Wooster [6J, who showed that benzene and its derivatives are reduced by sodium in liq uid ammonia in the presence of an alcohol, while this reaction does not take place in the absence of an alcohol. However, the general recognition and broad application of this reaction was achieved only after a series of investigations by Birch published from 1944 onwards [7J. Since the presence of an alcohol in the reaction medium is not indispen sable for pOlycyclic aromatic systems, the present review includes only deriv atives of the simplest aromatic compounds - benzene and naphthalene. 1 Reaction Mechanism The most probable mechanism of Birch reduction, adopted by the major ity of workers in this field [4, 8 -12] can be represented by the following stages: 'v\ I NH -'" ,. - i T 1 3 +--"'( a) , , ,e (NHa) NH 3) + ROH ----+ () ll. . (NHa) A H H 4) H H 5) ')', ",,\\+ + RO" ~ Q + 110M,,,,,, / (NHa) . (NH:,) Q H H Ii Ij H H H H H+ X/~H M,l
Reactions of Aromatic Compounds
Reactions of Aromatic Compounds
