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This volume provides a practical, intuitive approach to electroanalytical chemistry, presenting fundamental concepts and experimental techniques without the use of technical jargon or unnecessarily extensive mathematics. This edition offers new material on ways of preparing and using microelectrodes, the processes that govern the voltammetric behavior of microelectrodes, methods for characterizing chemically modified electrodes, electrochemical studies at reduced temperatures, and more. The authors cover such topics as analog instrumentation, overcoming solution resistance with stability and grace in potentiostatic circuits, conductivity and conductometry, electrochemical cells, carbon electrodes, film electrodes, microelectrodes, chemically modified electrodes, mercury electrodes, and solvents and supporting electrolytes.
It has been fashionable to describe electrochemistry as a discipline at the interface between the branches of chemistry and many other sciences. A perusal of the table of contents will affirm that view. Electrochemistry finds applications in all branches of chemistry as well as in biology, biochemistry, and engineering; electrochemistry gives us batteries and fuel cells, electroplating and electrosynthesis, and a host of industrial and technological applications which are barely touched on in this book. However, I will maintain that electrochemistry is really a branch of physical chemistry. Electrochemistry grew out of the same tradition which gave physics the study of electricity and magnet...
Researchers and professionals will find a hands-on guide to successful experiments and applications of modern electroanalytical techniques here. The new edition has been completely revised and extended by a chapter on quartz-crystal microbalances. The book is written for chemists, biochemists, environmental and materials scientists, and physicists. A basic knowledge of chemistry and physics is sufficient for understanding the described methods. Electroanalytical techniques are particularly useful for qualitative and quantitative analysis of chemical, biochemical, and physical systems. Experienced experts provide the necessary theoretical background of electrochemistry and thoroughly describe frequently used measuring techniques. Special attention is given to experimental details and data evaluation.
Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry...
There seems to be no end to the flood of conferences, workshops, panel discussions, reports and research studies calling for change in the introductory science courses in our colleges and universities. But, there comes a time to move from criticism to action. In 1993, the Division of Undergraduate Education of the National Science Foundation called for proposals for systemic initiatives to change the way int- ductory chemistry is taught. One of the five awards was to design, develop and implement the peer-led Workshop, a new structure to help students learn science. This book is a study of 15 years of work by the Peer-Led Team Learning (PLTL) project, a national consortium of faculty, learni...
Reflecting the growing volume of published work in this field, researchers will find this book an invaluable source of information on current methods and applications.
This volume is part of a continuing Electroanalytical Chemistry Series designed to provide authoritative reviews on recent developments and applications of well-established techniques in the field of electroanalytical chemistry. Electroanalytical techniques are used in such diverse areas as electro-organic synthesis, fuel cell studies, and radical ion formation. Each volume provides the necessary background and starting point for graduate students undertaking related research projects and is of special interest to practicing analytical chemists concerned with electroanalytical techniques. Each chapter provides comprehensive coverage of a subject area including detailed descriptions of techni...
A presentation of developments in the electrochemistry of C60 and related compounds, electroenzymatic synthesis, conducting polymers, and electrochemical partial fluorination. It contains accounts of carbonyl compounds, anodic oxidation of oxygen-containing compounds, electrosynthesis of bioactive materials, electrolyte reductive coupling, and more.
This book explores evidence-based practice in college science teaching. It is grounded in disciplinary education research by practicing scientists who have chosen to take Wieman’s (2014) challenge seriously, and to investigate claims about the efficacy of alternative strategies in college science teaching. In editing this book, we have chosen to showcase outstanding cases of exemplary practice supported by solid evidence, and to include practitioners who offer models of teaching and learning that meet the high standards of the scientific disciplines. Our intention is to let these distinguished scientists speak for themselves and to offer authentic guidance to those who seek models of excel...
When one considers the overall representation of frontier orbital filling of hexacoordinate (Oh) and tetracoordinate (Td) inorganic and organo metallic complexes, it clearly appears that out of 26 cases covering both high spin and low spin situations, 21 represent paramagnetic species (K. Purcell, J. Kotz, "Inorganic Chemistry", Saunders, 1977, p561). This would suggest that, if there is a part in chemistry to illustrate the reactivity of radical species, this part certainly is inorganic organometallic chemistry. In contrast with these expectations, and whereas the standard Organic Chemistry textbook (J. March ,"Advanced Organic Chemistry", J. Wiley, N. Y. , 1985) has a specific chapter devo...