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Detailing commonly used methods and procedures, this reference discusses the reactions and derivative forms of carbohydrates. Preparative Carbohydrate Chemistry covers the formation, cleavage, and reactions of derivatives and illustrates bond-forming reactions of SN2 types, free radicals, chain extensions, and branching. The contents include: sugar derivatives; selected reactions in carbohydrate chemistry; chemical synthesis of oligosaccharides and O-and N -glycosyl compounds; enzymatic synthesis of sialic acid, KDO, and related deoxyulosonic acids, and of oligosaccharides; synthesis of -glycosyl compounds; carbocycles from carbohydrates; and total synthesis of sugars from non-sugars. This authoritative reference offers relevant chapters on reactions and derivative forms of carbohydrates, including commonly used methods as well as new experimental procedures. It also contains insightful chapter commentaries and succinct topic histories.
To understand and improve the underlying principles that govern how organic reactions occur, A Foundation Course for College Organic Chemistry follows a brick-by-brick building approach. Emphasis is given to interrelating experimental facts and findings with predictions (mechanism) and inferences (results). Discussions focus on clarifying how complex organic reactions occur, which is based on electronegativity differences, movement of electrons (through σ framework or π bonds), and addition or removal of atoms (hydrogen, halogens) or groups (hydroxy, amino). The book begins with simple rules governing the deconstruction of reactions and applies them to explain how esterification, amide, an...
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