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The term "alloy" as pertaining to polymers has become an increasingly popular description of composites of polymers, parti cularly since the publication of the first volume in this series in 1977. Polymer alloy refers to that class of macromolecular materials which, in general, consists of combinations of chemically different polymers. The polymers involved in these combinations may be hetero geneous (multiphase) or homogeneous (single phase). They may be linked together with covalent bonds between the component polymers (block copolymers, graft copolymers), linked topologically with no covalent bonds (interpenetrating polymer networks), or not linked at all except physically (polyblends). I...
Because of a lack of appreciation for his efforts in developing modern polymer science, the contributions of Hermann Staudinger were disregarded for decades. There have also been delays in recognizing the contributions of other pioneers in polymer science. Hence, it is gratifying to note that Professor Seymour chaired an American Chemical Society Symposium focusing on the contributions of these pioneers and that Kluwer Academic Publishers has published the proceedings of this important symposium. H.Mark v DEDICATION This book on Pioneers in Polymer Science is dedicated to Nobel Laureate Polymer Scientists Hermann Staudinger, Emil Fischer, Herman Mark, Paul J. Flory, Linus Pauling, Carl S. Ma...
Alloy is a term commonly associated with metals and implies a composite which may be sinqle phase (solid solution) or heterophase. Whichever the case, metallic alloys generally exist because they exhibit improved properties over the base metal. There are numer ous types of metallic alloys, including interstitial solid solutions, substitutional solid solutions, and multiphase combinations of these with intermetallic compounds, valency compounds, electron compounds, etc. A similar situation exists with polymers. There are numerous types of composites, or "alloys" of polymers in existence today with new ones being created continuously. Polyblends are simple physical mixtures of the constituent polymers with no covalent bonds occuring between them. As with metals, these may be homogeneous (single phase) solid solytions or heterogeneous (multiple phase) mixtures. With polymers, the latter case is by far the most prevalent situation due to the thermodynamic incompatibility of most polymers. This is due to the relatively small gain in entropy upon mixing the polymers due to contiguity restrictions imposed by their large chain length.
This revolutionary and best-selling resource contains more than 200 pages of additional information and expanded discussions on zeolites, bitumen, conducting polymers, polymerization reactors, dendrites, self-assembling nanomaterials, atomic force microscopy, and polymer processing. This exceptional text offers extensive listings of laboratory exercises and demonstrations, web resources, and new applications for in-depth analysis of synthetic, natural, organometallic, and inorganic polymers. Special sections discuss human genome and protonics, recycling codes and solid waste, optical fibers, self-assembly, combinatorial chemistry, and smart and conductive materials.
Accompanied by an introductory overview of the history of polymer science, this book contains biographical sketches of 12 pioneers, from Marcellin Berthollet and John Wesley Hyatt to Karl Ziegler and Giulio Natta. It also includes time charts before each chapter that summarise significant events.
This history of the government-funded synthetic rubber research program (1942-1956) offers a rare analysis of a cooperative research program geared to the improvement of existing products and the creation of new ones. The founders of the program believed the best way to further research in the new field was through collaboration among corporations, universities, and the federal government. Morris concludes that, in fact, the effort was ultimately a failure and that vigorous competition proves the best way to stimulate innovation. Government programs, like the rubber research program, are far better at improving existing products, the author contends, than creating wholly new ones.
It would be difficult to overestimate the importance of polymer science to life in the twentieth century. Developments in polymer chemistry and engineering have led not only to the creation of a variety of substances such as synthetic fibers, synthetic rubber, and plastic but also to discoveries about proteins, DNA, and other biological compounds that have revolutionized western medicine. For these reasons, the history of the discipline tells an important story about how both our material and intellectual worlds have come to be as they are. Yasu Furukawa explores that history by tracing the emergence of macromolecular chemistry, the true beginning of modern polymer science. It is a lively book, given human interest through its focus on the work of two of the central figures in the development of macromolecular chemistry, Hermann Staudinger and Wallace Carothers. In Inventing Polymer Science, Furukawa examines the origins and development of the scientific work of Staudinger and Carothers, illuminates their different styles in research and professional activities, and contrasts the peculiar institutional and social milieux in which they pursued their goals.
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