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Army R, D & A.
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Ionic and Organometallic-Catalyzed Organosilane Reductions
Ionic and Organometallic-Catalyzed Organosilane Reductions provides an up-to-date, comprehensive review of reductions with organosilanes. Both ionic and catalyst-mediated reaction types are included, with appropriate reference to reaction mechanisms where they have been elucidated. The text also provides a wide variety of organic functional group reductions by organosilicon hydrides, and includes a substantial discussion of asymmetric reductions. All known examples have been compiled in thirty-four easily scanned, comprehensive tables compiled from 809 original articles. This is a must-have reference book for all synthetic organic chemists working in academic and industrial laboratories.
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Organic Reactions, Volume 83
The two chapters in Volume 83 describe reactions that represent two major (and growing) franchises in the Organic Reactions series, namely, transition metal catalyzed cross-coupling reactions and multicomponent reactions. These two processes not only have a rich history in synthetic organic chemistry, but also represent some of the most commonly employed transformations in the modern practice of molecule construction. The first chapter authored by Eiichi Nakamura, Takuji Hatakeyama, Shingo Ito, Kentaro Ishizuka, Laurean Ilies, and Masaharu Nakamura describes one of the most exiting advances in the field of transition metal catalyzed cross-coupling reactions: the use of iron catalysts. The second chapter authored by Stephen G. Pyne and Minyan Tang describes the latest in a long line of multicomponent reactions published in this series: the boronic acid Mannich reaction, sometimes called the Petasis reaction.
Organic Reactions, Volume 111
The 111th volume in this series for organic chemists in academia and industry presents critical discussions of widely used organic reactions or particular steps of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method. Volume contents: RING-OPENING REACTIONS OF EPOXIDES WITH TITANIUM(III) REAGENTS T. V. (Babu) RajanBabu, William A. Nugent, and Sandipan Halder REDUCTIVE CYCLIZATION OF 2-NITRO- AND β-NITROSTYRENES, 2-NITROBIPHENYLS, AND 1-NITRO-1,3-DIENES TO INDOLES, CARBAZOLES, AND PYRROLES Björn C. G. Söderberg and William F. Berkowitz
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