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This book deals with the phenomenological theory of first-order structural phase transitions, with a special emphasis on reconstructive transformations in which a group-subgroup relationship between the symmetries of the phases is absent. It starts with a unified presentation of the current approach to first-order phase transitions, using the more recent results of the Landau theory of phase transitions and of the theory of singularities. A general theory of reconstructive phase transitions is then formulated, in which the structures surrounding a transition are expressed in terms of density-waves, providing a natural definition of the transition order-parameters, and a description of the corresponding phase diagrams and relevant physical properties. The applicability of the theory is illustrated by a large number of concrete examples pertaining to the various classes of reconstructive transitions: allotropic transformations of the elements, displacive and order-disorder transformations in metals, alloys and related structures, crystal-quasicrystal transformations.
Since the development of the laser in the early 1960's, light scattering has played an increasingly crucial role in the investigation of many types of phase transitions and the published work in this field is now widely dispersed in a large number of books and journals.A comprehensive overview of contemporary theoretical and experimental research in this field is presented here. The reviews are written by authors who have actively contributed to the developments that have taken place in both Eastern and Western countries.
Ferroic materials are important, not only because of the improved understanding of condensed matter, but also because of their present and potential device applications. This book presents a unified description of ferroic materials at an introductory level, with the unifying factor being the occurrence of nondisruptive phase transitions in crystals that alter point-group symmetry. The book also aims to further systemitize the subject of ferroic materials, employing some formal, carefully worded, definitions and classification schemes. The basic physical principles leading to the wide-ranging applications of ferroic materials are also explained, while placing extra emphasis on the utilitarian role of symmetry in materials science.
Discontinuous (first-order) phase transitions constitute the most fundamental and widespread type of structural transitions existing in Nature, forming a large majority of the transitions found in elemental crystals, alloys, inorganic compounds, minerals and complex fluids. Nevertheless, only a small part of them, namely, weakly discontinuous transformations, were considered by phenomenological theories, leaving aside the most interesting from a theoretical point of view and the most important for application cases. Discontinuous Phase Transitions in Condensed Matter introduces a density-wave approach to phase transitions which results in a unified, symmetry-based, model-free theory of the w...
About half a century ago Landau formulated the central principles of the phe nomenological second-order phase transition theory which is based on the idea of spontaneous symmetry breaking at phase transition. By means of this ap proach it has been possible to treat phase transitions of different nature in altogether distinct systems from a unified viewpoint, to embrace the aforemen tioned transitions by a unified body of mathematics and to show that, in a certain sense, physical systems in the vicinity of second-order phase transitions exhibit universal behavior. For several decades the Landau method has been extensively used to an alyze specific phase transitions in systems and has been pro...
This 35th volume of the 'Studies' is devoted to the technologically important BSCCO system. It focuses on a host of topics such as the synthesis and fabrication of conductors, superconducting BSCCO magnets, and the basic technological properties of the material in relation to the microstructure. The authors are distinguished in the field, working in different parts of the world, maintaining the international character of the series.
The relative importance of oxides in the field of materials science has been spectacularly increasing during the last twenty years. First the study of ferroelectrics kept the attention of scientists. Nevertheless this domain is far from being worked out and a lot of new results and of new fields of interest were recently discovered.
The contents of this book stems from three different objectives. First, it is an introduction to the basic principles and techniques of Landau's theory, which is intended for teaching purposes. A second purpose of the book provides the practical methods for applying Landau's theory to complex systems. The last objective of the book is to incorporate the developments which have arisen in the last fifteen years from the extensive application of the theory to a variety of physical systems.
Structural Phase Transitions II, like its predecessor (Topics in Current Physics, Vol. 23), presents selected methods and recent advances in the experimental investigation of phase transitions in solids. The two chapters in this volume deal with electron paramagnetic resonance (EPR), and with nuclear magnetic and nuclear quadrupole resonance (NMR-NQR). Both techniques are particularly sensitive to local properties. The chapter on EPR concentrates largely on the investigation of static properties, including mean-field behaviour, critical and multicritical phenomena, whilst NMR is shown to be a powerful tool for studying nonlinear dynamics, incommensurate transitions, and disordered systems. This book will serve as an excellent introduction to the methodology and applications of EPR and NMR-NQR for all those wishing to become acquainted with these important tools for studying structural phase transitions.
Both an introductory course to broadband dielectric spectroscopy and a monograph describing recent dielectric contributions to current topics, this book is the first to cover the topic and has been hotly awaited by the scientific community.