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This text presents a balanced presentation of the macroscopic view of empirical kinetics and the microscopic molecular viewpoint of chemical dynamics. This second edition includes the latest information, as well as new topics such as heterogeneous reactions in atmospheric chemistry, reactant product imaging, and molecular dynamics of H + H2.
This unified treatment introduces upper-level undergraduates and graduate students to the concepts and methods of modern molecular spectroscopy and their applications to quantum electronics, lasers, and related optical phenomena. Starting with a review of the prerequisite quantum mechanical background, the text examines atomic spectra and diatomic molecules, including the rotation and vibration of diatomic molecules and their electronic spectra. A discussion of rudimentary group theory advances to considerations of the rotational spectra of polyatomic molecules and their vibrational and electronic spectra; molecular beams, masers, and lasers; and a variety of forms of spectroscopy, including optical resonance spectroscopy, coherent transient spectroscopy, multiple-photon spectroscopy, and spectroscopy beyond molecular constants. The text concludes with a series of useful appendixes.
The impact which has been made on spectroscopy by lasers, and by this route on major segments of physics and chemistry, has received ample documen tation in the past several years. Two principal themes emerge from examina tion of the numerous books and monographs now available on this subject: first, an increase in spectral resolution to levels previously undreamed of; and, second, the generation of nonlinear phenomena as a result of the intense radiation fields available from laser devices. There is one additional property of laser radiation which, although used extensively in experiments, does not appear to have been as thoroughly reviewed as the foregoing aspects. This is the spatial and ...
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First multi-year cumulation covers six years: 1965-70.