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Featuring contributions from leading experts, Organic Photochemistry and Photophysics is a unique resource that addresses the organic photochemistry and photophysical behavior in aromatic molecules, thiocarbonyls, selected porphyrins, and metalloporphyrins. The book presents theories pertaining to radiative and radiationless transitions. It
Key topics in this publication include semiconductor photochemistry and photoelectrochemistry, dye-sensitized solar cells and photocatalytic treatment of chemical waste. It discusses the commercialization and solar energy conversion of DSSC and the photocatalytic oxidation of air contaminants.
With contributions from 24 international authorities, Synthetic Organic Photochemistry offers a leading-edge presentation of the most recent and in-demand applications of photochemical methodologies. Outlining a wide assortment of reaction types entailing cycloadditions, cyclizations, isomerizations, rearrangements, and other organic syntheses, thi
This text examines organic, physical and materials photochemistry. It reports the first example of a TiO2 sensitization with a fullerene-based donor-acceptor dyad, and covers halophenols, diflusinal photochemistry, hydroxystyrenes, acetylenes, and other related compounds. The volume also investigates whether c,d-alkenes influence the efficiency and course of light-induced reactions, and more.
Control of molecular chirality is central to contemporary chemistry, biology, and materials-related areas. Chiral photochemistry employs molecular and supramolecular chiral interactions in the electronically excited state to induce molecular chirality, providing new and versatile strategies and surprising results unattainable by conventional therma
A state-of-the-art review of original research, this book includes discussions of intramolecular photoadditoin of nucleophiles, electrophiles, and radical species to the activated aromatic ring; new methods for regio-, anantio-, and diastereoselective photooxygenations involving singlet oxygen mechanisms; and applications of microreactors for photochemical synthesis of large-ring compounds, photochemical rearrangement, photocycloaddition, and chiral photochemical synthesis. It covers the role of layered inorganic solids in the construction, characterization, and analysis of supramolecular assemblies of metal ions, molecules, metal complexes, and proteins, and more.
Addressing critical aspects of computational modeling in photochemistry, Molecular Methods in Photochemistry is designed to familiarize researchers and practitioners with state-of-the-art computational methods to predict the reactivity of excited molecules. It provides practical guidelines and examples for the modeling of excited states and describ
This text discusses di-p-methane rearrangements via radical-cation intermediates, the photo-Fries rearrangement in organized media and of biologically active compounds, electron transfer leading to fragmentation, dimerization, and nucleophilic capture, and the characterization and reactivity of photochemically generated phenylene bis(diradical) spe
"Covers adsorption isotherms for polycyclic aromatic hydrocarbons and considers ground-stable stable and associate pairs. Describes the structure of inorganic layered materials and incalation of organic guest molecules in clays. Details photocyclization reaction in cyclodextrins, single-crystalline photochromism, and reaction dynamics in crystals, and more."
A consideration of the development of photochemical systems with functions as optical sensors or switches, discussing materials and chemical systems, technology, and applications for target molecules and optical signal multiplexing. It contains novel applications in electrogenerated chemiluminescence and supramolecular photophysics for sensing chemical and biological analytes.