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Organized to provide maximum utility to the bench synthetic chemist. The editor is well-known for his work in exploring, developing, and applying organopalladium chemistry. Contributors include over 24 world authorities in the field.
With contributions by numerous experts
With contribution by numerous experts
Improvement of the catalytic properties of biological catalysts is equally important in the optimization of industrial processes as in the fundamental understanding of the catalytic machinery at the molecular level. The approaches taken are diverse and span from purely result-oriented, but nevertheless methodologically subtle, making and screening of combinatorial libraries to highly sophisticated tailoring of the environment of active sites. This volume illustrates four different concepts for modifying a given biocatalyst framework or create novel functions using Nature's basic building blocks. Summing up the state-of-the-art biocatalyst engineering it, serves as an orientational landmark and a platform for the specialist and non-expert alike to keep abreast of developments in this rapidly evolving field.
Phosphorus chemistry is a diverse field and this volume focuses on new developments of "old themes" with different approaches and ideas, state of the art for two topics of general interest, and the emerging fields of research. This volume only describes in part the huge number of original papers on phosphorus-related topics.
I Reactivity: E. Uggerud: Physical Organic Chemistry of the Gas Phase. Reactivity Trends for Organic Cations.- S. Petrie, D.K. Bohme: Mass Spectrometric Approaches to Interstellar Chemistry.- F. Turecek: Transient Intermediates of Chemical Reactions by Neutralization-Reionization Mass Spectrometry.- II Metalorganic Chemistry: D. Schröder, H. Schwarz: Diastereoselective Effects in Gas-Phase Ion Chemistry.- D.A. Plattner: Metalorganic Chemistry in the Gas Phase: Insight into Catalysis.- III Mass Spectrometric Methodology: T. Wyttenbach, M.T. Bowers: Gas-Phase Conformations: The Ion Mobility/Ion Chromatography Method.- P.B. Armentrout: Threshold Collision-Induced Dissociations for the Determination of Accurate Gas-Phase Binding Energies and Reaction Barriers.- IV Medicinal Chemistry: S.A. Trauger, T. Junker, G. Siuzdak: Investigating Viral Proteins and Intact Viruses with Mass Spectrometry M. Brönstrup: High-Throughput Mass Spectrometry for Compound Characterization in Drug Discovery.
Knoevenagel Reaction of Unprotected Sugars, By M.-C. Scherrmann ; Carbohydrate-Based Lactones: Synthesis and Applications, By N. M. Xavier, A. P. Rauter, and Y. Queneau; Heterogeneously-Catalyzed Conversion of Carbohydrates, By K. De Oliveira Vigier and F. Jérôme; Palladium-Catalyzed Telomerization of Butadiene with Polyols: From Mono to Polysaccharides, By S. Bouquillon, J. Muzart, C. Pinel, and F. Rataboul; Monosaccharides, By J.A. Galbis and M.G. García-Martín; Natural Sources, By L. Weignerová and V. Křen; Synthesis and Applications of Ionic Liquids Derived from Natural Sugars; By C. Chiappe, A. Marra, and A. Mele
Following the first two volumes "Dendrimers" (TCC vol. 197) and "Dendrimers II" (TCC vol. 210), the third volume dealing with this topic is now appearing in print (the "tetralogy" on dendrimers will soon be completed with the fourth volume). The present volume comprises a collection of up-to-date reviews written by renowned pioneers of research in the dendrimer field, three of whom lectured at the 1. International Dendrimer Symposium (IDS-1 1999) in Frankfurt. A focus of this volume is the variety of material properties of soft and shape-persistent dendrimers. As its predecessors did, this volume breaks through the frontiers to neighboring disciplines and, in an interdisciplinary approach, addresses topics such as polydisperse, hyperbranched macromolecules (dendritic polymers), the analysis of shape and density by small-angle scattering techniques, finely dispersed metals (dendrimers as catalysts), and nanotechnology close to potential applications.
There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit [1]. The electronic and geometric properties of a molecule are inexorably linked and this is especially true with six-coordinate copper(II) compounds which are subject to a Jahn-T- ler effect.However,the spectral-structural correlations that are sometimes d- wn must often be viewed with caution as the information contained in a typical solution UV-Vis absorption spectrum of a copper(II) compound is li...