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Atomically dispersed metal cations and small polyatomic cationic structures co-ordinated to the surface of porous matrices exhibit different properties from the same cationic species contained in a bulk oxide or supported on amorphous carriers. This subject is treated to an extensive review, showing how an understanding of it is essential to the development of a new generation of solid catalysts. There are also exciting opportunities to shape the catalytic properties of the transition metal cations in microporous and mesoporous matrices. The book covers both theoretical and experimental aspects, including the distribution of framework Al atoms in Si-rich zeolites, distribution and siting of charge-exchanged metal cations, electronic, adsorptive and catalytic properties of metal cations, and correlation of metal cation structure and siting with catalytic activity.
New and Future Developments in Catalysis is a package of seven books that compile the latest ideas concerning alternate and renewable energy sources and the role that catalysis plays in converting new renewable feedstock into biofuels and biochemicals. Both homogeneous and heterogeneous catalysts and catalytic processes will be discussed in a unified and comprehensive approach. There will be extensive cross-referencing within all volumes.The various sources of environmental pollution are the theme of this volume. The volume lists all current environmentally friendly catalytic chemical processes used for environmental remediation and critically compares their economic viability. - Offers in-depth coverage of all catalytic topics of current interest and outlines future challenges and research areas - A clear and visual description of all parameters and conditions, enabling the reader to draw conclusions for a particular case - Outlines the catalytic processes applicable to energy generation and design of green processes
Zeolites are the most frequently used industrial catalysts. Their applications range from oil refining, petrochemistry and the synthesis of special chemicals to environmental catalysis. Rapid progress in basic research and the development of new processes has resulted in the first Federation of European Zeolite Associations (FEZA) School on Zeolites. Zeolites and Ordered Mesoporous Materials: Progress and Prospects reflects the programme of the first School on Zeolites, held in Prague on August 20-21, 2005. Readers gain insight into the synthesis of the ever-expanding spectrum of zeolites, zeotypes and ordered mesoporous materials including the use of zeolites and mesoporous materials as cat...
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The twelfth Congress on Catalysis was held in Granada (Spain) under the auspices of the International Association of Catalysis Societies and the Spanish Society of Catalysis. These four-volume Proceedings are the expression of the Scientific Sessions which constituted the main body of the Congress.They include 5 plenary lectures, 1 award lecture, 8 keynote lectures, 124 oral presentations and 495 posters. The oral and poster contributions have been selected on the basis of the reports of at least two international reviewers, according to standards comparable to those used for specialised journals.
These proceedings reflect recent developments in the field of zeolite chemistry and catalysis with an emphasis on the role of a modifying component on the properties of the molecular sieve material. The plenary lectures and contributed papers concentrate on the problem of isomorphous substitution in a zeolitic framework; on the occlusion and the structure of metal, metal oxide, and metal sulphide clusters and complexes in the intracrystalline void volume of molecular sieves and zeolites as well as in the interlaminar space of layered compounds.Catalytic applications are discussed, not only in regard to traditional hydrocarbon transformation, but also in such areas as: reduction of SO2, decomposition of NO, reactions of sulphur containing compounds and conversion of CO, CO2 to hydrocarbons or of alcohols to oxygenated products.Because the book provides valuable data and information on new achievements in the zeolite material science and application, it will be of considerable interest to all research groups involved in zeolite science.
There is an increasing challenge for chemical industry and research institutions to find cost-efficient and environmentally sound methods of converting natural resources into fuels chemicals and energy. Catalysts are essential to these processes and the Catalysis Specialist Periodical Report series serves to highlight major developments in this area. This series provides systematic and detailed reviews of topics of interest to scientists and engineers in the catalysis field. The coverage includes all major areas of heterogeneous and homogeneous catalysis and also specific applications of catalysis such as NOx control kinetics and experimental techniques such as microcalorimetry. Each chapter...
Introduction to Zeolite Molecular Sieves, 3rd Edition presents a collection of the most important results and ideas in the field of molecular sieve chemistry and technology, the most important experimental techniques related to the research activities in molecular sieves, and identifies new areas of molecular sieve chemistry. Chapters start at a reasonably simple entry level, but also covers the present state-of-the-art in the field. Topics covered include structure, synthesis, characterization, ion exchange, adsorption, diffusion, separations, and natural zeolites.* 6 years since the last edtion this book brings together the rapid development within the field of molecular sieve chemistry and applications * Accessible to newcomers to the field, also containing valuable information for experienced researchers * 27 chapters written by renowned scientists in their field, including updates on some 2nd edition chapters
Metal Microstructures in Zeolites
ZEOCAT '95 is the eleventh in the series of symposia devoted to special fields of zeolite chemistry. Six plenary lectures, forty oral and forty-two poster presentations were included in the program. The accepted papers cover every aspect of catalysis on microporous materials. A significant number of the contributions describe the synthesis, modification, instrumental and chemical characterisation of zeolites and other micro- and mesoporous materials. Catalytic reactions involve hydrocarbon cracking, nucleophilic aromatic substitution, methanol to hydrocarbon conversion, hydration of acetylene, various alkylation reactions, redox transformations, Claisen rearrangement, etc.