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Comprehensive Organic Functional Group Transformations
This Volume, which is in three parts, includes some of the most important functional groups of organic chemistry. Part I deals with the synthesis of carboxylic acids and their derivatives (acid halides, esters, amides etc.) together with their imino-, thio-, seleno and telluro analogues. Part II covers cumulenes such as isocyanates, isothiocyanates, carbodiimides and related compounds, whilst Part III deals with triply bonded functional groups.
Comprehensive Organic Functional Group Transformations
A vast range of different functional groups is potentially available from the attachment of three or four heteroatoms to carbon. Some of these are abundantly represented in the literature, others are rare, and many have yet to be described. The aim of this volume is to describe the synthesis of examples of known functional groups and to highlight those that are little known or unknown. All possible combinations of heteroatoms have been surveyed, with the exception of complexes in which carbon atoms are bonded only to transition elements. The material is organised in four parts: tetracoordinated carbon atoms bearing three attached heteroatoms are covered in Part 1, and those bearing four heteroatoms in Part II; the synthesis of tricoordinated carbon atoms with three attached heteroatoms is described in Part III; stabilized radicals and carbocations with three attached heteroatoms are covered briefly in Part IV.
Comprehensive Organic Functional Group Transformations
In this Volume, containing 24 chapters devoted to carbon attached by single bonds to two heteroatoms, the reader will find several chapters reviewing the synthesis of familiar functional groups, notably acetals, dithioacetals, aminals and the various mixed species. The derivatives with tetracoordinated (saturated) carbon are described in Part I and those, eg. ketene acetals, of tricoordinated carbon in Part II. However, the treatment is comprehensive and the authors have uncovered much fascinating chemistry concerning less familiar groups, including some like geminal halohydrins, halo amines and diols that are often unstable. Again, a surprisingly large number of compounds having two metals ...
Comprehensive Organic Functional Group Transformations, Volume 3
Volume 3 summarises contemporary methods for the synthesis of functional groups where carbon is attached to a heteroatom (notably oxygen, nitrogen, and sulphur) by a double or triple bond. The synthesis of all types of carbon and heteroatom substituted, and unsaturated derivatives are brought together in a coherent fashion, and where possible emphasis has been placed on selectivity and efficiency, together with practical applications in real situations in synthetic chemistry. Thus, the Volume covers synthetic methods for aldehydes and ketones, together with their sulphur (ie. thioaldehydes and thioketones), selenium, tellurium, nitrogen (ie. imines, oximes and hydrazones, including iminium salts and diazo compounds), phosphorus and metal/metalloid analogues. Synthetic methods for heteroatom substituted aldehydes and ketones and their analogues, eg. carbonyl ylides, are also included, and a thorough account of ketenes and ketenimines and their various heteroatom and metal analogues is given. The Volume also covers the unique chemistry associated with the synthesis of nitriles and N-substituted nitriles, together with isonitriles and all their heteroanalogues.
Comprehensive Organic Functional Group Transformations
This Volume covers the formation of carbon-carbon single-, double- and triple bonds by substitution and addition reactions as well as by various rearrangements. The formation of carbon-carbon multiple bonds by elimination and condensation procedures is fully documented. In addition the synthesis of carbon-hydrogen bonds principally by substitution and addition reactions is featured as is the preparation of a wide variety of carbon-centred anions, cations and radicals.
