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Cyclopropanes in Organic Synthesis
This is a practical guidebook about cyclopropanes that thoroughly surveys derivatives and transformations, synthetic methods, and experimental efficiency as a gateway for further research and development in the field. • Provides comprehensive lists and synthetically-oriented synopses of cyclopropane chemistry review references along with publication data on applications in the syntheses of natural and related biologically active compounds • Acts as a resource to help readers better understand cyclopropane applications for the efficient realization of synthetically important organic transformations and popular experimental procedures • Includes new developments and up-to-date informatio...
Synthesis of Cyclopropane Hydrocarbons from Methylcyclopropyl Ketone
The following properties of the hydrocarbons were determined: melting point, boiling point, index of refraction, density, and net heat of combustion. The infrared spectra of 2-cyclopropylpropene, 2-cyclopropylpropane, and methylcyclopropyl ketone are presented.
Cyclopropane Derived Reactive Intermediates Updates
An expanded and updated version of "Cyclopropyl Radicals, Anion Radicals and Anions" contributed to the 1987 volume, "The Chemistry of the Cyclopropyl Group" by Rappaport. It includes recent investigations of cyclopropane cation radicals in the gas phase, in solutions and in matrices.
The Chemistry of the Cyclopropyl Group (NY Handling Set Only)
The latest in a series of advanced treatises under the general editorship of Professor Saul Patai providing a comprehensive review of the chemistry of the cyclopropyl group including physical properties, analysis, reaction mechanisms and synthetic uses.
Small Ring Compounds in Organic Synthesis VI
This current and five previous volumes (Volumes 133, 135, 144, 155, 178) convincingly demonstrate the vast applications of small rings in modern Organic Synthesis. Such applications range from total syntheses of cyclopropyl-group-containing natural products and non-natural biologically active compounds or compounds with other important properties (e.g. liquid crystalline) via syntheses of cyclopropyl analogues of natural and non-natural physiologically active compounds, e.g. peptidomimetics, to the use of cyclopropyl groups as reactive subunits in so-called composite functional groups. This current volume covers a survey of the wide range of biological activities of cyclopropyl-containing compounds, up-to-date comprehensive reviews on the multiple applicabilities of two multifunctional small ring building blocks - methyl-2-chloro-2-cyclopropylidene acetate and bicyclopropylidene - in Organic Synthesis as well as a striking new approach to cyclopentenones from easily accessible 1-ethynylcyclopropanols, which is rather general and favorably complements other cyclopentenone syntheses.
Donor-Acceptor Cyclopropanes in Organic Synthesis
Donor-Acceptor Cyclopropanes in Organic Synthesis Facilitate milder, simpler reactions in organic synthesis with this cutting-edge family of building blocks Donor-Accepted Cyclopropanes, or DACs, have attracted a resurgence of interest from organic chemists in recent decades for their role in facilitating various reactions such as cycloadditions, annulations, ring-opening and enantioselective transformations. The structural arrangement of DACs leads to milder, simpler reaction conditions, which have made them indispensable for a range of fundamentally and industrially important processes. Donor-Acceptor Cyclopropanes in Organic Synthesis covers comprehensively the chemistry and applications ...
