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Silicon dioxide plays a central role in most contemporary electronic and photonic technologies, from fiber optics for communications and medical applications to metal-oxide-semiconductor devices. Many of these applications directly involve point defects, which can either be introduced during the manufacturing process or by exposure to ionizing radiation. They can also be deliberately created to exploit new technologies. This book provides a general description of the influence that point defects have on the global properties of the bulk material and their spectroscopic characterization through ESR and optical spectroscopy.
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Noncrystalline (NC) solids, as is well known, lack the long range order of crystals. Accordingly, they exhibit scattering, e.g., x-ray, electron, and neutron, but not the diffraction patterns characteristic of crystals. The intensity distributions from NC solids are usually transformed into radial distribution functions (RDF), but the interpretation of the RDF's is not unique. The lack of long-range order, and the non-uniqueness of the structural interpretation, have constituted the main obstacles to the usual solid state physics approach which has been so successful in dealing with crystals. As a corrolary, questions of local order and structure have frequently been de-emphasized. This mono...
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