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Photochemistry and Photophysics of Metal Complexes
  • Language: en
  • Pages: 364

Photochemistry and Photophysics of Metal Complexes

Focusing on practical applications, the author provides a balanced introduction to the many possible technological uses of metal complexes. Coverage includes the transition metals, lanthanide and actinide complexes, metal porphyrins, and many other complexes. This volume meets the needs of students and scientists in inorganic chemistry, chemical physics, and solid-state physics.

Multiple Bonds between Metal Atoms
  • Language: en
  • Pages: 840

Multiple Bonds between Metal Atoms

Provides historical perspective as well as current data Abundantly illustrated with figures redrawn from literature data Covers all pertinent theory and physical chemistry Catalytic and chemotherapeutic applications are included

Inorganic Reactions and Methods, The Formation of Bonds to N, P, As, Sb, Bi (Part 2)
  • Language: en
  • Pages: 514

Inorganic Reactions and Methods, The Formation of Bonds to N, P, As, Sb, Bi (Part 2)

For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.

Scorpionates: The Coordination Chemistry Of Polypyrazolylborate Ligands
  • Language: en
  • Pages: 294

Scorpionates: The Coordination Chemistry Of Polypyrazolylborate Ligands

This book deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966, but becoming rapidly popular with inorganic, organometallic and coordination chemists since 1986, because of their versatility and user-friendliness. They can be readily modified sterically and electronically through appropriate substitution on the pyrazole ring and on boron, and have led to a number of firsts in coordination chemistry (first stable CuCO complex, first monomeric MgR complex, and many other such firsts). Their denticity can range from two to four, their “Bite” can be adjusted, and additional coordinating sites can be added to the pyrazolyl rings. Over 170 different scorpionate l...

Homogeneous Catalysis with Metal Phosphine Complexes
  • Language: en
  • Pages: 494

Homogeneous Catalysis with Metal Phosphine Complexes

The field of transition metal catalysis has experienced incredible growth during the past decade. The reasons for this are obvious when one considers the world's energy problems and the need for new and less energy demanding syntheses of important chemicals. Heterogeneous catalysis has played a major industrial role; however, such reactions are generally not selective and are exceedingly difficult to study. Homogeneous catalysis suffers from on-site engineering difficulties; however, such reactions usually provide the desired selectivity. For example, Monsanto's synthesis of optically-active amino acids employs a chiral homogeneous rhodium diphosphine catalyst. Industrial uses of homogeneous catalyst systems are increasing. It is not by accident that many homogeneous catalysts contain tertiary phosphine ligands. These ligands possess the correct steric and electronic properties that are necessary for catalytic reactivity and selectivity. This point will be emphasized throughout the book. Thus the stage is set for a comprehensive be treatment of the many ways in which phosphine catalyst systems can designed, synthesized, and studied.

Electron Spin Resonance
  • Language: en
  • Pages: 376

Electron Spin Resonance

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The A...

Calixarenes 2001
  • Language: en
  • Pages: 692

Calixarenes 2001

Calixarene chemistry, at the turn of the millennium, is a field approaching true maturity. In many areas, applications are real and important, and the arsenal of structures based on calixarenes provides tools effective in numerous areas of supramolecular chemistry. In this book, chapters contributed by a broad spectrum of international authors provide a variety of perspectives upon the progress and future of calixarene chemistry. Issues covered in depth include: Calixarene synthesis, with all its subtleties and sophistication. Forces at play in the inclusion of neutral and charged molecules by calixarenes. Theoretical analyses of calixarene properties. Dynamics and thermodynamics of calixarenes and their complexes. Nanocomposite construction based on calixarene aggregates. Calixarenes on surfaces. Analytical applications of calixarenes. Catalysis by calixarenes and their complexes. Resource recovery and waste treatment with calixarenes. New directions in calixarene chemistry. Hetero- and homo-calixarenes. Bioactive calixarenes. Coordination chemistry of calixarenes. Calixarenes in the solid state.

Annual Reports on NMR Spectroscopy
  • Language: en
  • Pages: 369

Annual Reports on NMR Spectroscopy

NMR spectroscopy has grown to be a vitally important technique with applications in many areas of science. Annual Reports on NMR Spectroscopy is quickly becoming the source for the latest information on current progress, both experimental and theoretical. Chemists in a variety of disciplines will be interested in this up-to-date, comprehensive series.

Inorganic Syntheses
  • Language: en
  • Pages: 326

Inorganic Syntheses

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.