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Sustainable Heavy Metal Remediation
This book covers the principles, underlying mechanisms, thermodynamic functions, kinetics and modeling aspects of sustainable technologies, particularly from the standpoint of applying physical, chemical and biological processes for the treatment of wastewater polluted with heavy metals. Particular emphasis has been given to technologies that are based on adsorption, electro-coagulation, bio-precipitation, bio-solubilization, phytoremediation and microbial electrolysis. Metal contamination in the environment is one of the persisting global issues. The adverse health effects of heavy metals on human beings and its impact on the environment has been well-documented. Several physico-chemical an...
Separation Processes
Contributed articles presented at an International Conference on Separation Processes organized by Institute of Chemical Engineering & Technology, Institute of Technology, Banaras Hindu University in 2009.
Sustainable Heavy Metal Remediation
This book presents an assortment of case-studies pertaining to the use of sustainable technologies for heavy metal removal and recovery from mining and metallurgical wastes, construction and demolition wastes, spent catalysts and electronic wastes. Wastewaters from diverse industrial and mining activities have caused pollution problems, but these sectors also serve as a hotspot for metal recovery. Several metal removal technologies based on physical, chemical and biological processes have been successfully implemented in full-scale operation, while metal recovery, which is beneficial for economic and environmental reasons, is still limited due to challenges arising from downstream processing...
Anaerobic Oxidation of Methane Coupled to the Reduction of Different Sulfur Compounds as Electron Acceptors in Bioreactors
This research investigated new approaches to control anaerobic methane oxidation coupled to sulfate reduction (AOM-SR) and enrich anaerobic methanotrophs (ANME) and sulfate reducing bacteria (SRB) with the purpose of designing a suitable bioreactor for AOM-SR at ambient pressure and temperature. The current knowledge about AOM and the microorganisms involved in AOM are discussed. The effect of different substrates and pressures was investigated on the ANME and SRB community adapted to the shallow marine Lake Grevelingen, the Netherlands. Further, microorganisms from the Alpha Mound (Spain) deep sediment were enriched with methane gas as substrate in biotrickling filters (BTF) at ambient cond...
Bioreduction of Selenite and Tellurite by Phanerochaete Chrysosporium
Selenium (Se) and tellurium (Te) are metalloids of commercial interest due to their physicochemical properties. The water soluble oxyanions of these elements (selenite, selenate, tellurite and tellurate) exhibit high toxicities; hence, their release in the environment is of great concern. This study demonstrates the potential use of fungi as Se- and Te-reducing organisms. The response of Phanerochaete chrysosporium to the presence of selenite and tellurite was evaluated, as well as its potential application in wastewater treatment and production of nanoparticles. Growth stress and morphological changes were induced in P. chrysosoporium when exposed to selenite and tellurite. Synthesis of Se0...
Optimization of the Electron Donor Supply to Sulphate Reducing Bioreactors Treating Inorganic Wastewater
The main objective of this research was to optimize the electron donor supply in sulphate reducing bioreactors treating sulphate rich wastewater. Two types of electron donor were tested: lactate and slow release electron donors such as carbohydrate based polymers and lignocellulosic biowastes. Biological sulphate reduction was evaluated in different bioreactor configurations: the inverse fluidized bed, sequencing batch and batch reactors. The reactors were tested under steady-state, high-rate and transient-state feeding conditions of electron donor and acceptor, respectively. The results showed that the inverse fluidized bed reactor configuration is robust and resilient to transient and high-rate feeding conditions at a hydraulic retention time as low as 0.125 d. The biological sulphate reduction was limited by the COD:sulphate ratio ( 82% either using carbohydrate based polymers or lignocellulosic bio-wastes, in batch bioreactors. The biological sulphate reduction was limited by the hydrolysis-fermentation rate and by the complexity of the slow release electron donors.
Metal Recovery from Electronic Waste: Biological Versus Chemical Leaching for Recovery of Copper and Gold
Waste electrical and electronic equipment (WEEE) generation is a global problem. Despite the growing awareness and deterring legislation, most of the WEEE is disposed improperly, i.e. landfilled or otherwise shipped overseas, and treated in sub-standard conditions. Informal recycling of WEEE has catastrophic effects on humans and the environment. WEEE contains considerable quantities of valuable metals such as base metals, precious metals and rare earth elements (REE). Metal recovery from WEEE is conventionally carried out by pyrometallurgical and hydrometallurgical methods. In this PhD research, novel metal recovery technologies from WEEE are investigated. Using acidophilic and cyanide-gene...
The Diplomatic Pulse
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The Pulse
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