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Free Radicals in Biology and Environment
Our understanding of the quantitative aspects of free radical chemistry and the involvement of radicals in such areas as biology, medicine, the environment, etc., has developed spectacularly over recent years, yet the various topics are commonly discussed separately, in specific meetings and specialised publications. Free Radicals in Biology and Environment draws together two important areas of free radical chemistry, using as a bridge the fundamental physical chemistry of free radicals (spectroscopic detection of free radicals, evaluation of absolute rate constants, elucidation of mechanisms of free radical reactions and catalysis, photochemical and radiation processes, etc.). The most rele...
Chemical Processes in Atmospheric Oxidation
Oxidation and removal of atmospheric constituents involve complex sequences of reactions which can lead to the production of photo-oxidants such as ozone. In order to understand and model these complex reaction sequences, it is necessary to have a comprehensive understanding of reaction mechanisms and accurate estimates of kinetic parameters for relevant gas-phase atmospheric reactions. This book presents recent advances in the field and includes the following topics: e.g. the oxidation of simple organic compounds, NOx kinetics and mechanisms, OH radical production and rate constants for the OH attack on more complex organic compounds, peroxy and alkoxy radical reactions, photo-oxidation of aromatic and biogenic compounds, and the interaction between radical species.
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Atmospheric Environmental Research
This is an extended version of lectures that were held at the summer workshop Atmosphiirische Umweltforschung im Spannungsfeld zwischen Technik und Natur (At mospheric Environmental Research between Technology and Nature) at the Techni 16, 1996. We were very happy to have Paul J. Crutzen, cal University in Cottbus on July winner of the Nobel Prize for chemistry in 1995, presenting the key lecture on glo bally changing chemistry in the atmosphere. Over the last decades, atmospheric chem istry has been established step by step, not just as an applied discipline of chemistry, but also as a key discipline for our understanding of air pollution, biogeochemical cycling, and climactic processes as ...
Photo-oxidants, Acidification and Tools: Policy Applications of EUROTRAC Results
EUROTRAC is the EUREKA environmental project studying the transport and chemical transformation of pollutants in the troposphere over Europe. At its inception in 1988 it had three aims: * to increase the basic understanding of atmospheric science; * to promote the technological development of sensitive, specific, fast-response instrumentation for environmental research and monitoring; and * to improve the scientific basis for taking future political decisions on environmental management within Europe. It was clear at an early stage, as the fourteen subprojects were formed and more than two hundred research groups in twenty-four countries were incorporated, that the first aim would readily be achieved. An ample demonstration that the early indications were correct is provided in the other volumes in this series which describe the scientific progress made. Substantial progress was also made towards achieving the second aim although some problems were encountered, mainly due to the high cost of the technological development required.
Heterogeneous and Liquid Phase Processes
The "European Experiment on the Transport and Transformation of Environmentally Relevant Trace Constituents over Europe" (EUROTRAC) was established in 1986 to tackle the scientific problem and combine the expertise, knowledge and resources in Europe, in order to apply them over a large region covering the greater part of the continent. EUROTRAC is a coordinated multidisciplinary scientific research project involving field measurements, laboratory studies, instrument development and development of comprehensive computer models for the simulation of the physical and chemical processes in the lower atmosphere.
Instrument Development for Atmospheric Research and Monitoring
Jens Bosenberg Max-Planck-Institut fur Meteorologie, Bundesstr. 55, D-20146 Hamburg, Germany TESLAS, which stands for Tropospheric Environmental Studies by Laser Sounding, was formed in November 1987 as a subproject of EUROTRAC to enhance the measurement capabilities for vertical profiling of ozone in the troposphere by means of laser remote sensing. For studies of several atmospheric processes related to the formation and redistribution of photo-oxidants there was a clear need for measuring extended time series with appropriate vertical and temporal resolution. These could not be obtained by conventional in situ techniques, at least not with affordable effort, so remote sensing appeared to ...
Biosphere-Atmosphere Exchange of Pollutants and Trace Substances
The biosphere is the ultimate sink for air pollutants and is also the source of many precursors for the formation of photo-oxidants. In any analysis of air pollution and for determining source-receptor relationships, reliable emission and pollutant concentrations or depositions must be taken into account, together with their interactions between the atmosphere and the biosphere. This book presents a number of authoritative review articles covering topics which include biosphere-atmosphere exchange of ammonia, nitrogen oxides, ozone and sulfur-containing gases, the biological mechanisms involved in the exchange of trace gases, as well as generalizations of deposition over Europe.
Cloud Multi-phase Processes and High Alpine Air and Snow Chemistry
Among the chemical and physical processes involved in the transformation of pollutants between their sources and their ultimate deposition, those associated with clouds, aerosols and precipitation must be rated as the most difficult both to study and to understand. This book presents a variety of recent advances in this field, including the properties and composition of aerosol particles, chemical transformation and scavenging processes, the relationship between liquid-phase chemistry and cloud micro-physics, entrainment, evaporation and deposition, trends in high Alpine pollution, transport processes, and developments in instrumentation. This book is Volume 5 in the ten-volume series on Transport and Chemical Transformation of Pollutants in the Troposphere.
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