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The most useful reactions of organonitro compounds in organic synthesis Compounds containing nitro groups are useful intermediates for the synthesis of natural products and other complex organic molecules. The Nitro Group in Organic Synthesis focuses on reactions that proceed under mild conditions, important functional groups that can be synthesized by conversion of nitro groups, and the stereoselectivity of reactions of nitro compounds. These issues are of great importance to practicing researchers in today's pharmaceutical, agrochemical, and fine chemical industries. The Nitro Group in Organic Synthesis also emphasizes environmentally-friendly methods for nitration, the importance of aliphatic nitro compounds, and modern preparation of nitro compounds. Other topics discussed include: * Henry reaction * Asymmetric Michael addition * Alkylation, acylation, halogenation, and related reactions of RNO2 * Substitution and elimination of NO2 and RNO2 The Nitro Group in Organic Synthesis is a useful resource for researchers and students in organic and medicinal chemistry.
This volume brings together contributions by leading researchers covering a wide scope so characteristic of fluorine chemistry. It is a monograph of historical character comprising personalized accounts of progress and events in areas of particular interest.There is also much to interest and instruct chemists from other disciplines as a good proportion of the chapters contain a considerable amount of 'hard' referenced information relating to modern organic, organoelemental and inorganic chemistry. Historians of chemistry and technology will no doubt be tempted to dip into this book, and surely whoever addresses the task of commemorating Moissan's achievement at the 150-years stage will bless us all in some measure for its existence.
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This multi-authored work reviews and evaluates the growing importance of the nitro group function. It describes the powerful influence of the nitro group on recent progress in organic synthesis and emphasizes recent developments in the chemistry of this group. The contributors consider the increasingly significant role of organic nitro chemistry in providing a source of new reagents and in offering selective transformations. They provide a detailed review of nitrogen pentoxide chemistry which stresses its usefulness as a nitrating agent for various classes of organic compounds. Researchers, students and teachers will benefit from the combined knowledge and expertise of the authors. The editor has worked and taught in many countries. He has published extensively on organic nitrogen compounds and has discovered new methods. Special feature: Contains the first complete survey of aliphatic fluoronitro chemistry.