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Crystallization Modalities in Polymer Melt Processing
Structure formation in crystallizing polymers, as occurring during processing, has not been treated so far in a coherent form. This fact explains, why this monograph is written as the ?rst book devoted to this subject. A quarter of a century ago the underdevelopment of this subject was obvious. Trial and error dominated. In fact, other apposite subjects as polymer melt rheology or heat transfer, had reached high levels. A great number of books has been devoted to them. Mold ?lling of amorphous polymers and the solidi?cation of these polymers by vitri?cation can nowadays be simulated numerically with a high degree of accuracy. In the solidi?ed sample even residual stresses and corresponding b...
Polymer Melt Rheology and Flow Birefringence
The present monograph is intended as an introduction into a field which certainly did not receive proper attention in the past. It is one of the aims of this book to verify this suppo sition. The author hopes to show that the technique of the measurement of flow birefringence can fulfil an important com plementary task in polymer melt rheology. From this point it is expected that the present monograph will attract the atten tion of polymer scientists in general, and of rheologists and process engineers in particular. Certainly, the fourth chapter will appeal to the latter group. As a teacher in polymer science and technology the author wants to address also the group of the graduate students...
Rheology: An Historical Perspective
The science of rheology remains a mystery to most people, even to some scientists. Some respectable dictionaries have been quite cavalier in their attitude to the science, the small Collins Gem dictionary, for example, being quite happy to inform us that a Rhea is an three-toed South American ostrich, whilst at the same time offering no definition of rheology. This maybe due to the fact that the science is interdisciplinary and does not fit well into any one of the historical disciplines. This book contains an in-depth study of the history of rheology, beginning with the statements of Heraclitus, Confucius and the prophetess Deborah. It also emphasises the distinctive contributions of Newton...
A Century of Fluid Mechanics in The Netherlands
In October 1918, Jan Burgers, 23 years old, started as professor of ‘aerodynamics, hydrodynamics, and their applications’ at the Technical University in Delft. This can be regarded as the birth of fluid mechanics in the Netherlands, not only as an academic discipline but also as the start of the serious study of flow phenomena in engineering environments. During the period of Burgers’ tenure in Delft (till 1955) three Dutch institutes were founded which to this day remain important centres of research in various fields of fluid mechanics: aerospace engineering, hydraulics, and naval engineering. Burgers and others developed mathematical, experimental, and numerical approaches of a broa...
Macromolecular Design of Polymeric Materials
Providing a range of information on polymers and polymerization techniques, this text covers the gamut of polymer science from synthesis, structure and properties to function and applications. It analyzes speciality polymers, including acrylics, fluoropolymers, polysiplanes, polyphosphazenes, and inorganic and conducting polymers. The book examines the stereochemistry of polymerization and the stereoregularity of polymers.
Rheo-Physics of Multiphase Polymer Systems
FROM THE PREFACE Almost all polymeric systems are subjected to a flow field at least once along the route between preparation and application. . . . There is also an increased interest in predictive models on phase behavior and suitable techniques for characterizing the structure of these systems when subjected to flow. Multiphase polymeric systems are particularly susceptible to flow, which may cause orientation of species, morphological changes, and phase transitions. All these events may, in turn, affect the end product properties, such as permeability, electrical conductivity, [and] mechanical properties. In processing, escalating needs have evolved for optimization and development of no...
The Phenomenological Theory of Linear Viscoelastic Behavior
One of the principal objects of theoretical research in any department of knowledge is to find the point of view from which the subject appears in its greatest simplicity. J. Willard Gibbs This book is an outgrowth of lectures I have given, on and off over some sixteen years, in graduate courses at the California Institute of Technology, and, in abbreviated form, elsewhere. It is, nevertheless, not meant to be a textbook. I have aimed at a full exposition of the phenomenological theory of linear viscoelastic behavior for the use of the practicing scientist or engineer as well as the academic teacher or student. The book is thus primarily a reference work. In accord with the motto above, I have chosen to describe the theory of linear viscoelastic behavior through the use of the Laplace transformation. The treatment oflinear time-dependent systems in terms of the Laplace transforms of the relations between the excitation add response variables has by now become commonplace in other fields. With some notable exceptions, it has not been widely used in viscoelasticity. I hope that the reader will find this approach useful.
Flow-Induced Crystallization of Polymers
In polymer processing, the molecular orientation induced by flow has a significant effect on the crystallization kinetics and final morphology of the polymer produced. The impact on processing operations and object properties is extremely important and recently scientific and technological researchers have begun to quanitify these effects. The international conference 'Flow-Induced Crystallization of Polymers', held in October 2001 in Salerno, Italy, was timely and well attended. An interdisciplinary approach was taken and presentations were made on topics ranging from real-time measurement, through modelling, to final morphology and properties of polymers. Invited and other selected contributions from the conference are collected here, in this volume of Macromolecular Symposia
