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Mass Spectrometry of Inorganic and Organometallic Compounds
This is the first modern book to treat inorganic and organometallic mass spectrometry simultaneously. It is textbook and handbook in one; as a textbook it introduces the techniques and gives hints on how to apply the various techniques, as a handbook it lists all available ionization techniques for just about any given compound. The book also includes non-mathematical explanations of how modern MS instruments work Mass Spectrometry of Inorganic and Organometallic Compounds will inspire the synthetic inorganic and organometallic chemist with the confidence to apply some of the new techniques to their characterization problems.
Transition Metal Carbonyl Cluster Chemistry
Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demons...
New Methodology for Probing Catalytic Reactions by ESI-MS.
Bis(dimethylamino)-2-(4-methoxyphenyl)naphthalene (3) and 1,8-bis(dimethylamino)-4-diphenylphosphonaphthalene (5b) were synthesized as ESI-active analogues of the common organometallic ligands?6-anisole and triphenylphosphine. The water-soluble phosphine, sodium triphenylphosphine monosulfonate, was re-purposed as an ESI-active ligand. Its solubility in organic solvents and amenability to electrospray ionization was improved by replacing Na+ with the non-coordinating bis(triphenylphosphine)iminium cation. A new sample introduction method named PSI (pressurized sample infusion) was developed for the continuous infusion of air/moisture-sensitive samples into the mass spectrometer. The flow rat...
Charged Ligands for Direct ESI-MS Analysis of Catalytic Reactions
Electrospray ionization mass spectrometry (ESI-MS) is well-established in the detection of large fragile organic molecules such as polymers, peptides and proteins. The study of catalysis by transition metal complexes is complicated by difficulties including ligand lability, complex neutrality and air- and moisture-sensitivity. This work is focused on establishing methods to solve these problems and to apply them to well-understood systems in order to establish credibility before applying them to new systems. Attempts to synthesize a 2,2'-bipyridine (bipy)-type ligand designed to have proton sponge-like properties after binding to a metal are presented. The synthesis of 3,3'-N, N'-bis(dimethy...
Introduction to Coordination Chemistry
At the heart of coordination chemistry lies the coordinate bond, in its simplest sense arising from donation of a pair of electrons from a donor atom to an empty orbital on a central metalloid or metal. Metals overwhelmingly exist as their cations, but these are rarely met ‘naked’ – they are clothed in an array of other atoms, molecules or ions that involve coordinate covalent bonds (hence the name coordination compounds). These metal ion complexes are ubiquitous in nature, and are central to an array of natural and synthetic reactions. Written in a highly readable, descriptive and accessible style Introduction to Coordination Chemistry describes properties of coordination compounds such as colour, magnetism and reactivity as well as the logic in their assembly and nomenclature. It is illustrated with many examples of the importance of coordination chemistry in real life, and includes extensive references and a bibliography. Introduction to Coordination Chemistry is a comprehensive and insightful discussion of one of the primary fields of study in Inorganic Chemistry for both undergraduate and non-specialist readers.
Bioinorganic Chemistry -- Inorganic Elements in the Chemistry of Life
The field of Bioinorganic Chemistry has grown significantly in recent years; now one of the major sub-disciplines of Inorganic Chemistry, it has also pervaded other areas of the life sciences due to its highly interdisciplinary nature. Bioinorganic Chemistry: Inorganic Elements in the Chemistry of Life, Second Edition provides a detailed introduction to the role of inorganic elements in biology, taking a systematic element-by-element approach to the topic. The second edition of this classic text has been fully revised and updated to include new structure information, emerging developments in the field, and an increased focus on medical applications of inorganic compounds. New topics have bee...
Chirality in Transition Metal Chemistry
Chirality in Transition Metal Chemistry is an essential introduction to this increasingly important field for students and researchers in inorganic chemistry. Emphasising applications and real-world examples, the book begins with an overview of chirality, with a discussion of absolute configurations and system descriptors, physical properties of enantiomers, and principles of resolution and preparation of enantiomers. The subsequent chapters deal with the the specifics of chirality as it applies to transition metals. Some reviews of Chirality in Transition Metal Chemistry "...useful to students taking an advanced undergraduate course and particularly to postgraduates and academics undertakin...
Spectroscopic Properties of Inorganic and Organometallic Compounds
Reflecting the growing volume of published work in this field, researchers will find this book an invaluable source of information on current methods and applications.
Lanthanide and Actinide Chemistry
LANTHANIDE AND ACTINIDE CHEMISTRY Lanthanides and actinides, also known as “f elements,” are a group of metals which share certain important properties and aspects of electronic structure. They have a huge range of applications in the production of electronic devices, magnets, superconductors, fuel cells, sensors, and more. The cursory treatment of these important metals in most inorganic chemistry textbooks makes a book-length treatment essential. Since 2006, Lanthanide and Actinide Chemistry has met this need with a thorough, accessible overview. With in-depth accounts of the lanthanides, actinides, and transactinides, this book is ideal for both undergraduate and postgraduate students...
Structural Methods in Molecular Inorganic Chemistry
Determining the structure of molecules is a fundamental skill that all chemists must learn. Structural Methods in Molecular Inorganic Chemistry is designed to help readers interpret experimental data, understand the material published in modern journals of inorganic chemistry, and make decisions about what techniques will be the most useful in solving particular structural problems. Following a general introduction to the tools and concepts in structural chemistry, the following topics are covered in detail: • computational chemistry • nuclear magnetic resonance spectroscopy • electron paramagnetic resonance spectroscopy • Mössbauer spectroscopy • rotational spectra and rotational...
