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Comprehensive Organic Synthesis: Additions to and substitutions at C-C[pi]-Bonds
Volume 4 focuses on additions and the resulting substitutions at carbon-carbon &pgr;-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient &pgr;-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to &pgr;-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.
Advanced Organic Chemistry
The two-part, fifth edition of Advanced Organic Chemistry has been substantially revised and reorganized for greater clarity. The material has been updated to reflect advances in the field since the previous edition, especially in computational chemistry. Part B describes the most general and useful synthetic reactions, organized on the basis of reaction type. It can stand-alone; together, with Part A: Structure and Mechanisms, the two volumes provide a comprehensive foundation for the study in organic chemistry. Companion websites provide digital models for students and exercise solutions for instructors.
Workbook for Organic Synthesis: The Disconnection Approach
One approach to organic synthesis is retrosynthetic analysis. With this approach chemists start with the structures of their target molecules and progressively cut bonds to create simpler molecules. Reversing this process gives a synthetic route to the target molecule from simpler starting materials. This “disconnection” approach to synthesis is now a fundamental part of every organic synthesis course. Workbook for Organic Synthesis: The Disconnection Approach, 2nd Edition This workbook provides a comprehensive graded set of problems to illustrate and develop the themes of each of the chapters in the textbook Organic Synthesis: The Disconnection Approach, 2nd Edition. Each problem is fol...
Synthetic Organic Photochemistry
Of all major branches of organic chemistry, I think none has undergone such a rapid, even explosive, development during the past twenty-five years as organic photochemistry. Prior to about 1960, photochemistry was still widely regarded as a branch of physical chemistry which might perhaps have oc casional applications in the generation of free radicals. Strangely enough, this attitude to the subject had developed despite such early signs of promise as the photodimerization of anthracene first observed by Fritzsche in 1866, and some strikingly original pioneering work by Ciamician and Silber in the early years of this century. These latter workers first reported such varied photo reactions as...
Thiophene and Its Derivatives, Volume 44, Part 4
The Chemistry of Heterocyclic Compounds, since its inception, has been recognized as a cornerstone of heterocyclic chemistry. Each volume attempts to discuss all aspects – properties, synthesis, reactions, physiological and industrial significance – of a specific ring system. To keep the series up-to-date, supplementary volumes covering the recent literature on each individual ring system have been published. Many ring systems (such as pyridines and oxazoles) are treated in distinct books, each consisting of separate volumes or parts dealing with different individual topics. With all authors are recognized authorities, the Chemistry of Heterocyclic Chemistry is considered worldwide as the indispensable resource for organic, bioorganic, and medicinal chemists.
Advances in Heterocyclic Chemistry
Four of the chapters in the fourth volume of Advances in Heterocyclic Chemistry deal with topics which have never been reviewed before. The first simple isothiazole was studied by Dr. R. Slack in 1956, and he and Dr. K. R. H. Wooldridge review in their article the considerable progress which has been made since then. Similarly the discovery of the widespread occurrence of covalent hydration has been achieved by the Canberra School, and we now have authoritative reviews on the qualitative (Drs. A. Albert and W. L. F. Armarego) and quantitative (Dr. D. D. Perrin) aspects of covalent hydration. Following the realization of the importance of aryne intermediates in benzenoid chemistry, work has b...
Arsenic and Old Mustard: Chemical Problems in the Destruction of Old Arsenical and `Mustard' Munitions
More than ten million `poison gas' shells, mortar bombs, etc., lie hidden in Europe, many of them relics from World War I. Some were fired and failed to detonate, others were abandoned in old ammunition dumps. Most retain their load of chemical warfare (CW) agents. They are turned up daily in the course of farming and construction. Many European nations have permanent departments concerned with their collection and destruction. Old munitions, when discovered, are usually heavily corroded and difficult to identify. Is it a CW munition? Or an explosive? If CW, what agent does it contain? Once identified, one has to select a destruction method. Some of the methods that have been proposed are less than perfect, and are often complicated by the presence of extraneous chemicals, either mixed with the CW agents during manufacture or formed over decades in the ground. Of particular interest are the insiders' reports on the German CW programmes of both World Wars, and the current status of Russian chemical armaments.
Progress in Physical Organic Chemistry
Progress in Physical Organic Chemistry is dedicated to reviewing the latest investigations into organic chemistry that use quantitative and mathematical methods. These reviews help readers understand the importance of individual discoveries and what they mean to the field as a whole. Moreover, the authors, leading experts in their fields, offer unique and thought-provoking perspectives on the current state of the science and its future directions. With so many new findings published in a broad range of journals, Progress in Physical Organic Chemistry fills the need for a central resource that presents, analyzes, and contextualizes the major advances in the field. The articles published in Pr...
Studies on Chemistry of Aromatic Nucleophilic Substitution Reaction in Solvents of Low Relative Permittivity
This book is based on a partial fulfillment of my doctoral thesis, which was finished about 20 years ago. This book is composed of 7 chapters. In the present work, the author is trying to describe his contribution to the chemistry of a fundamental unit reaction, bimolecular aromatic nucleophilic substitution (SNAr) reaction, with the hope of leaving something for the welfare of the human being.
Progress in Heterocyclic Chemistry
Progress in Heterocyclic Chemistry (PHC) Volume 6 reviews critically the heterocyclic literature essentially published in 1993. The first two chapters are given over to reviews. In Chapter 1 the fascinating subject of the "Halogen Dance" is comprehesively surveyed by J. Frohlich of the Technical University of Vienna. The author also discusses some of his unpublished results on the topic. The second review is of an entirely new format for PHC. The President of ISHC A. Padwa describes the application of selected "Heterocycles as Vehicles for Synthesis". The remaining chapters describe advances in the heterocyclic field arranged, as in previous volumes, according to ring-size. Numerous diagrams and a brief index are also included.
