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Metal and metalloid-containing compounds exhibit a wide range of biological and biocidal activities, some of which have been employed in medicines and drugs. Polymers containing metal or metalloid functions become a natural extension of this effort; just as organic compound drugs have been chemically bound to polymers or physically imbibed into polymer matrices in order to provide a variety of useful advantages, the same opportunities exist for using metal and metalloid species. This volume will cover important biomedical applications of organometallic compounds, including metal-labeled DNA on surfaces, artificial metallo-DNA, organotin molecules as anti-cancer drugs, and much more. * Provides useful descriptions of biomedical applications for the reader to apply in his/her research into materials, polymers, and medicine/drug development. * Edited by high-quality team of macromolecular experts from around the world
Metal- and metalloid-containing macromolecules are defined as large molecules (i.e., polymers, DNA, proteins) that contain a metal or metalloid group affiliated with the molecule. Compiled by an all-star cast of macromolecular experts, Macromolecules Containing Metal and Metal-Like Elements, Volume 2, Organoiron-Containing Polymers: Provides useful descriptions of applications for the reader to apply in his/her research into materials, polymers, and medicine/drug development. Covers non-linear optical materials, speciality magnetic materials, liquid crystals, anticancer and antiviral drugs, treatment of arthritis, antibacterial drugs, antifouling materials, treatment of certain vitamin deficiencies, electrical conductors and semiconductors, piezoelectronic materials, electrodes, UV absorption applications, super-strength materials, special lubricants and gaskets, selective catalytic and multisite catalytic agents.
Research on metal-containing polymers began in the early 1960's when several workers found that vinyl ferrocene and other vinylic transition metal u -com plexes would undergo polymerization under the same conditions as conventional organic monomers to form high polymers which incorporated a potentially reactive metal as an integral part of the polymer structures. Some of these materials could act as semi-conducters and pos sessed one or two dimensional conductivity. Thus appli cations in electronics could be visualized immediately. Other workers found that reactions used to make simple metal chelates could be used to prepare polymers if the ligands were designed properly. As interest in homo geneous catalysts developed in the late 60's and early 70's, several investigators began binding homogeneous catalysts onto polymers, where the advantage of homo geneous catalysis - known reaction mechanisms and the advantage of heterogeneous catalysis - simplicity and ease of recovery of catalysts could both be obtained. Indeed the polymer matrix itself often enhanced the selectivity of the catalyst.
Metal- and metalloid-containing macromolecules are defined as large molecules (i.e., polymers, DNA, proteins) that contain a metal or metalloid group affiliated with the molecule. The first volume in this series consists of a number of reviews of the field, to give the reader a background to build upon. Compiled by an all-star cast of macromolecular experts, this guide: Provides useful descriptions of applications for the reader to apply in his/her research into materials, polymers, and medicine/drug development. Covers non-linear optical materials, speciality magnetic materials, liquid crystals, anticancer and antiviral drugs, treatment of arthritis, antibacterial drugs, antifouling materials, treatment of certain vitamin deficiencies, electrical conductors and semiconductors, piezoelectronic materials, electrodes, UV absorption applications, super-strength materials, special lubricants and gaskets, selective catalytic and multisite catalytic agents.
Research on metal-containing polymers began in the early 1960's when several workers found that vinyl ferrocene and other vinylic transition metal TI -complexes would undergo polymerization under the same conditions as conventional organic monomers to form high polymers which incorporated a potentially reactive metal as an integral part of the polymer structures. Some of these materials could act as semi conductors and possessed one or two dimensional conductivity. Thus applications in electronics could be visualized immediately. Other workers found that reactions used to make simple metal chelates could be used to prepare polymers if the ligands were designed properly. As interest in homoge...
The IUPAC 8th International Symposium on Macromolecule-Metal Complexes (MMC-8 Tokyo) was held at the International Conference Center of Waseda University, Tokyo in September 1999. Topic areas presented included several basic and applied topics in the field of advanced MMC such as preparation, characterization and fundamental aspects, macromolecules for advanced technologies including the sub-topics of electron- and ion conductors, separation, adsorption, transport of gas molecules, electronic-, magnetic-, photonic properties, catalysis and photocatalysis, liquid crystals, and biological-, medical- and environmental use.