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Understanding Voltammetry (Fourth Edition)
The power of electrochemical measurements in respect of thermodynamics, kinetics and analysis is widely recognised but the subject can be unpredictable to the novice even if they have a strong physical and chemical background, and most especially if they wish to pursue quantitative measurements. Accordingly, some significant experiments are perhaps wisely never attempted, while the literature is sadly replete with flawed attempts at rigorous voltammetry.This textbook considers how to go about designing, explaining and interpreting experiments centred on various forms of voltammetry (cyclic, microelectrode, hydrodynamic, etc.). The reader is assumed to have knowledge of physical chemistry equ...
Understanding Voltammetry
Preface to the second edition -- Preface to the first edition - Introduction -- Mathematical model of an electrochemical system -- Numerical solution of the model system -- Diffusion-only electrochemical problems in one-dimensional systems -- First-order chemical kinetic mechanisms -- Second-order chemical kinetic mechanisms -- Electrochemical simulation in weakly supported media -- Hydrodynamic voltammetry -- Two-dimensional systems: microdisc electrodes -- Heterogeneous surfaces -- Stochastic electrochemistry.
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Critical Psychiatry
This book is a guide for psychiatrists struggling to incorporate transformational strategies into their clinical work. The book begins with an overview of the concept of critical psychiatry before focusing its analytic lens on the DSM diagnostic system, the influence of the pharmaceutical industry, the crucial distinction between drug-centered and disease-centered approaches to pharmacotherapy, the concept of “de-prescribing,” coercion in psychiatric practice, and a range of other issues that constitute the targets of contemporary critiques of psychiatric theory and practice. Written by experts in each topic, this is the first book to explicate what has come to be called critical psychiatry from an unbiased and clinically relevant perspective. Critical Psychiatry is an excellent, practical resource for clinicians seeking a solid foundation in the contemporary controversies within the field. General and forensic psychiatrists; family physicians, internists, and pediatricians who treat psychiatric patients; and mental health clinicians outside of medicine will all benefit from its conceptual insights and concrete advice.
Herstellung organischer Solarzellen mit den Verfahren der elektrochemischen und elektrophoretischen Abscheidung
Das Ziel der vorliegenden Arbeit ist die Beantwortung der Frage, ob und unter welchen Voraussetzungen organische Solarzellen mit den Verfahren der elektrochemischen bzw. elektrophoretischen Abscheidung hergestellt werden können. Basierend auf den Kenntnissen der elektrochemischen Synthese werden in der vorliegenden Arbeit die wesentlichen Materialgruppen, die für den Bau organischer Solarzellen notwendig sind, elektrochemisch bzw. elektrophoretisch abgeschieden. Die zu untersuchenden Materialgruppen umfassen die chemischen Verbindungen der Übergangsmetalloxide, Polymere, kleinen Moleküle und Polymergemische. Die Abscheidung der Materialschichten erfolgt mit einem Drei-Elektroden-Aufbau, dessen elektrolytische Zellen eigens konstruiert wurden. Mit den gewonnenen Erkenntnissen zur Schichtabscheidung werden die Materialschichten der organischen Solarzelle zuerst teilweise und schlussendlich vollständig elektrochemischen bzw. elektrophoretischen abgeschieden.
