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This book covers fundamentals of organometal perovskite materials and their photovoltaics, including materials preparation and device fabrications. Special emphasis is given to halide perovskites. The opto-electronic properties of perovskite materials and recent progress in perovskite solar cells are described. In addition, comments on the issues to current and future challenges are mentioned.
Perovskite is a well-known structure with the chemical formula ABX3, where A and B are cations coordinated with 12 and 6 anions, respectively, and X is an anion. When a halogen anion is used, the monovalent A and divalent B cations can be stabilized with respect to a tolerance factor ranging from ~0.8 to 1. Since the first report on ~10% efficiency and long-term stability of solid-state perovskite solar cells (PSCs) in 2012 and two subsequent seed reports on perovskite-sensitized solar cells in 2009 and 2011, PSCs have received increasing attention. The power conversion efficiency of PSCs was certified to be more than 25% in 2020, surpassing thin-film solar cell technologies. Methylammonium ...
Covering both organic materials, where recent advances in the understanding of device physics is driving progress, and the newly emerging field of mixed halide perovskites, which are challenging the efficiencies of conventional thin film PV cells, this book provides a balanced overview of the experimental and theoretical aspects of these solar cell classes. Emphasis is placed on understanding the fundamental physics of the devices. The book also discusses modelling over many length scales, from nano to macro. The first book to cover perovskites, this is an important reference for industrialists and researchers working in energy technologies and materials.
Perovskite Photovoltaics and Optoelectronics Discover a one-of-a-kind treatment of perovskite photovoltaics In less than a decade, the photovoltaics of organic-inorganic halide perovskite materials has surpassed the efficiency of semiconductor compounds like CdTe and CIGS in solar cells. In Perovskite Photovoltaics and Optoelectronics: From Fundamentals to Advanced Applications, distinguished engineer Dr. Tsutomu Miyasaka delivers a comprehensive exploration of foundational and advanced topics regarding halide perovskites. It summarizes the latest information and discussion in the field, from fundamental theory and materials to critical device applications. With contributions by top scientis...
Photovoltaic systems enable the sun’s energy to be converted directly into electricity using semiconductor solar cells. The ultimate goal of photovoltaic research and development is to reduce the cost of solar power to reach or even become lower than the cost of electricity generated from fossil and nuclear fuels. The power conversion efficiency and the cost per unit area of the phototvoltaic system are critical factors that determine the cost of photovoltaic electricity. Until recently, the power conversion efficiency of single-junction photovoltaic cells has been limited to approximately 33% - the so-called Shockley-Queisser limit. This book presents the latest developments in photovolta...
Due to the pressing needs of society, low cost materials for energy devices have experienced an outstanding development in recent times. In this highly multidisciplinary area, chemistry, material science, physics, and electrochemistry meet to develop new materials and devices that perform required energy conversion and storage processes with high efficiency, adequate capabilities for required applications, and low production cost. Nanostructured Energy Devices: Equilibrium Concepts and Kinetics introduces the main physicochemical principles that govern the operation of energy devices. It includes coverage of the physical principles that control energy devices made of nanostructured and bulk ...
The scientific community and industry have seen tremendous progress in efficient energy production and storage in the last few years. With the advancement in technology, new devices require high-performance, stretchable, bendable, and twistable energy sources, which can be integrated into next-generation wearable, compact, and portable electronics for medical, military, and civilian applications. Smart and Flexible Energy Devices examines the materials, basic working principles, and state-of-the-art progress of flexible devices like fuel cells, solar cells, batteries, and supercapacitors. Covering the synthesis approaches for advanced energy materials in flexible devices and fabrications and...
The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
This book addresses the principles and materials for the development of next-generation solar cells for a sustainable global society Discusses the structures, working principles, and limitations of solar cells as well as the improvement methods of their power-conversion efficiency Introduces generations of cells as photovoltaic devices, including third-generation solar cells such as organic solar cells, quantum dots solar cells, and organic–inorganic hybrid solar cells Focuses on the emerging perovskite solar cells (PSCs) and deals with their cell configuration, transport materials, and fabrication processes in detail.
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