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Neutron Scattering
Neutron Scattering
Polymers in Solution
Polymers in Solution was written for scientists and engineers who have serious research interests in newer methods for characterization of polymer solutions, but who are not seasoned experts in the theoretical and experimental aspects of polymer science. In particular, it is assumed that the reader is not familiar with the development of theoretical notions in conformational statistics and the dynamics of chainlike molecules; how these two seemingly diverse theoretical topics are related; and the role played by polymer-solvent interactions. Chapter 1 thus presents background material that introduces most of the essential concepts, including some of the mathematical apparatus most commonly us...
Thermodynamics of Polymer Blends, Volume I
Thermodynamics is an indispensable tool for developing a large and growing fraction of new polymers and polymer blends. These two volumes show the researcher how thermodynamics can be used to rank polymer pairs in order of immiscibility, including the search for suitable chemical structure of compatibilizers. Because of the great current commercial interest in this most dynamic sector of the polymer industry, there is high interest in studying their physical and mechanical properties, their structures, and the processes of their formation and manufacture. These Books are dedicated to Analysis of the Thermodynamics of Polymer Blends. Thermodynamic behavior of blends determines the compatibility of the components, their morphological features, rheological behavior, and microphase structures. As a result, the most important physical and mechanical characteristics of blends can be identified. The information in these two volumes will be useful to all those involved in polymer research, development, analysis and advanced process engineering.
Viscoelastic Behavior of Rubbery Materials
The enormous size of polymer molecules causes their molecular motions to span a broad range of length scales and give rise to viscoelastic behaviour. This rate-dependence of the properties is a predominant characteristic of soft materials (rubbers, biopolymers, lubricants, adhesives, etc.). Improving the performance and developing new applications for soft materials require an understanding of the basic principles of how molecular motions underlie physical properties. This text is intended to provide grounding in fundamental aspects of the dynamic behavior of rubbery materials, adopting a molecular perspective in its treatment to emphasize how microscopic processes are connected to the observed macroscopic behavior. The latest discoveries and advances in the science and technology of rubbery materials are described and critically analyzed.
Static and Dynamic Properties of the Polymeric Solid State
This volume contains the major portion of the material given at the NATO Advanced Study Institute, held at the University of Strathclyde, Glasgow, UK. , September 6th-18th, 1981. The original idea germin ated in a conversation between the organisers on a cold December night in 1978 in the depths of the Oxfordshire countryside. At that time we felt that the chemical physics of macromolecules in the solid state was running on two parallel tracks, namely structure and dynamics. The contact between the two appeared to be slight. We were also concerned that the degree of srecial knowledge now required for any one technique essentially prevented people from learning the important features of other...
Scattering Techniques Applied to Supramolecular and Nonequilibrium Systems
This Advanced Study Institute was held at \-lellesley College, Wellesley, MA. , from 3 to 12 August 1980. It followed by four years the second "Capri ~,chool on Photon Correlation Spectroscopy". During the intervening period there had been many new applications of dynamic light scattering techniques to the study of systems whose properties depend either on collective molecular interactions or on the formation or activity of supramo1ecu1ar structures. Con sequently, emphasis at this conference was on light scattering studies of subjects such as dynamical correlations in dense polymer solutions, phase transitions in gels, spinodal decomposition of binary fluids, Benard instabilities in nonequi...
Advanced Routes for Polymer Toughening
This volume is an account of the various approaches used to improve the toughness of polymer matrices. The correlations among the molecular structure of the components, the morphology and the mechanical properties of blend systems are stressed. Emphasis is placed on the methods used to control the structure of these materials during processing.The book concentrates on a number of systems which may be regarded as typologies of toughened plastics. From an extensive treatment of these systems more general concepts have been developed. These concepts which are indispensable in the design and formulation of tough polymer blends, include the role of the interface in multicomponent systems, the che...
Structure and Properties of Ionomers
Ionomers, that is polymers containing a low concentration of charged units along the chain, have been the subject of increasing interest during the past twenty years. The presence of ionic groups in the poly mer changes some of its properties dramatically. Increases in the modu lus and the viscosity of several orders of magnitude have been observed, and changes in the glass transition of hundreds of degrees are possible. In addition, diffusion coefficients can be modified drastically. These changes are due primarily to the presence of reversible ionic cross links in these materials. Because of the low dielectric constant of most organic polymers, the ions or ionic dipoles tend to aggregate ; this aggregation process, however, is limited, because the ionic groups are covalently bonded to the organic chain. Host of the fundamental research done on these materials has been devoted to a determination of the extent of association, the structure of the aggregates, the limi ting factors, and the correlations between molecular and supermolecular structure and the resul ting properties.
Polypropylene Structure, blends and Composites
Although polypropylene has been marketed since the 1950s, research and development in this area is still vigorous. The consumption of polypropylene over the years has been relatively high, mainly due to the steady improvement of its property profile. Polypropylene: Structures, Blends and Composites, in three separate volumes, reflects on the key factors which have contributed to the success of polypropylene, dealing with all aspects of structure-performance relationships relevant to thermoplastic polymers and related composites. Volume 1, Structure and Morphology, deals with polymorphism in polypropylene homo- and copolymers, where molecular and supermolecular structures are covered, and the...
Nanoscale Materials
Organized nanoassemblies of inorganic nanoparticles and organic molecules are building blocks of nanodevices, whether they are designed to perform molecular level computing, sense the environment or improve the catalytic properties of a material. The key to creation of these hybrid nanostructures lies in understanding the chemistry at a fundamental level. This book serves as a reference book for researchers by providing fundamental understanding of many nanoscopic materials.
