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The y-induced decomposition of ethyl ether, in the liquid phase and in the gas phase, were investigated. In the pure liquid ether radiolysis, the major products were hydrogen (G^=3.70), 2,3-diethoxybutane (G=2.63), ethanol (G = 2.13), ethane (G=1.27), ethylene (G^=l.l), ethyl vinyl ether (G-1.13), and s-butyl ethyl ether (0=0.74). Only hydrogen and ethylene yields were found to decrease with increasing dose. The decrease of ethylene yield might be the result of radical scavenging and secondary reactions with some products whereas the decrease in hydrogen yield might be due to free ion scavenging as well. Binary solutions of ether with ethyl vinyl ether, benzene, and 1,3-pentadiene were also ...
Fuels represent an important aspect of world economy. The study of the chemical properties and compositions of fuels is necessary to provide a better understanding of their reactions, and, possibly, to promote their improved commercial utilization. Spectrometry comprises a valuable group of tools and techniques for the study of fuels and their derivatives. Some of the undesirable by-products from fuels-specifically, pollutants-provide the spectroscopist with an additional vast area for the application of his tools. The fight against pollution of all kinds has spawned one of our most rapidly growing industries. It thus seems pertinent to devote a book to the spectrometric investiga tion of fu...
Special edition of the Federal Register, containing a codification of documents of general applicability and future effect ... with ancillaries.