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Presenting a completely new approach to examining how polymers move in non-dilute solution, this book focuses on experimental facts, not theoretical speculations, and concentrates on polymer solutions, not dilute solutions or polymer melts. From centrifugation and solvent dynamics to viscosity and diffusion, experimental measurements and their quantitative representations are the core of the discussion. The book reveals several experiments never before recognized as revealing polymer solution properties. A novel approach to relaxation phenomena accurately describes viscoelasticity and dielectric relaxation and how they depend on polymer size and concentration. Ideal for graduate students and researchers interested in the properties of polymer solutions, the book covers real measurements on practical systems, including the very latest results. Every significant experimental method is presented in considerable detail, giving unprecedented coverage of polymers in solution.
This textbook for graduates and advanced undergraduates in physics and physical chemistry covers the major areas of statistical mechanics and concludes with the level of current research. It begins with the fundamental ideas of averages and ensembles, focusing on classical systems described by continuous variables such as position and momentum, and using the ideal gas as an example. It then turns to quantum systems, beginning with diatomic molecules and working up through blackbody radiation and chemical equilibria. The discussion of equilibrium properties of systems of interacting particles includes such techniques as cluster expansions and distribution functions and uses non-ideal gases, liquids, and solutions. Dynamic behavior -- treated here more extensively than in other texts -- is discussed from the point of view of correlation functions. The text concludes with the problem of diffusion in a suspension of interacting hard spheres and what can be learned about such a system from scattered light. Intended for a one-semester course, the text includes several "asides" on topics usually omitted from introductory courses, as well as numerous exercises.
With the mapping of the partition function graphs of the n-vector magnetic model in the n to 0 limit as the self-avoiding walks, the conformational statistics of linear polymers was clearly understood in early seventies. Various models of disordered solids, percolation model in particular, were also established by late seventies. Subsequently, investigations on the statistics of linear polymers or of self-avoiding walks in, say, porous medium or disordered lattices were started in early eighties. Inspite of the brilliant ideas forwarded and extensive studies made for the next two decades, the problem is not yet completely solved in its generality. This intriguing and important problem has re...
Condensed matter is an active field of physics, with a stream of discoveries in areas from superfluidity and magnetism to the optical, electronic and mechanical properties of materials such as semiconductors, polymers and carbon nanotubes. This book presents research in this field.
James Dunnigan’s memorable phrase serves as the first part of a title for this book, where it seeks to be applicable not just to analog wargames, but also to board games exploring non-expressly military history, that is, to political, diplomatic, social, economic, or other forms of history. Don’t board games about history, made predominantly out of (layered) paper, permit a kind of time travel powered by our imagination? Paper Time Machines: Critical Game Design and Historical Board Games is for those who consider this a largely rhetorical question; primarily for designers of historical board games, directed in its more practice-focused sections (Parts Two, Three, and Four) toward those ...
Combining materials science, mechanics, implant design and clinical applications, this self-contained text provides a complete grounding to the field.
"Provides a physical interpretation of the data obtained in macromolecular transport phenomena in a given system and also addresses some important issues and concepts related to biopolymers such as proteins and nucleic acids"--