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Fullerenes
Fullerene, molekulare "Fu?balle" aus 60 oder mehr Kohlenstoffatomen, sind eine Substanzklasse mit vielversprechenden Zukunftsaussichten, beispielsweise als Halbleiter, als Basis pharmazeutischer Wirkstoffe oder Polymerwerkstoffe. Dieses Buch bietet Ihnen einen aktuellen Uberblick uber das dynamische Forschungsgebiet. Zur Sprache kommen modernste Themen wie Metallofullerene, Nanorohren und organisch funktionalisierte Fullerenverbindungen. (06/00)
The Physics of Fullerene-Based and Fullerene-Related Materials
Krätschmer and Huffman's revolutionary discovery of a new solid phase of carbon, solid C60, in 1990 opened the way to an entire new class of materials with physical properties so diverse that their richness has not yet been fully exploited. Moreover, as a by-product of fullerene research, carbon nanotubes were later identified, from which novel nanostructures originated that are currently fascinating materials scientists worldwide. Rivers of words have been written on both fullerenes and nanotubes, in the form of journal articles, conference proceedings and books. The present book offers, in a concise and self-contained manner, the basics of the science of these materials as well as detaile...
Superconductivity
This book provides readers with a comprehensive overview of the science of superconducting materials. It serves as a fundamental information source on the actual techniques and methodologies involved in superconducting materials growth, characterization and processing. This book includes coverage of several categories of medium and high-temperature superconducting materials: cuprate oxides, borides, and iron-based chalcogenides and pnictides. Provides a single-source reference on superconducting materials growth, characterization and processing; Bridges the gap between materials science and applications of superconductors; Discusses several categories of superconducting materials such as cuprate oxides, borides, and iron-based chalcogenides and pnictides; Covers synthesis, characterization, and processing of superconducting materials, as well as the nanoengineering approach to tailor the properties of the used materials at the nanoscale level.
Progress In Fullerene Research - Proceedings Of The International Winterschool On Electronic Properties Of Novel Materials
The proceedings summarise the oral and poster presentations of the Winterschool on the above topic. The event was the sixth in a series aimed at describing and discussing recent advances in the understanding of the electronic properties of novel materials. The topic of the meeting, fullerenes and related materials, was chosen as a sequel to that of the previous year in an effort to keep abreast of this new and rapidly evolving field of research. For the duration of the week, world experts from the fields of physics, chemistry and materials science were gathered together to present their current research as well as to participate in the many lively discussions which evolved from the presentations. As such, the proceedings constitute a definitive description of the state of the art of fullerene research.
50 Years of Structure and Bonding – The Anniversary Volume
Chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the ...
Ab Initio Studies on Superconductivity in Alkali-Doped Fullerides
This book covers high-transition temperature (Tc) s-wave superconductivity and the neighboring Mott insulating phase in alkali-doped fullerides. The author presents (1) a unified theoretical description of the phase diagram and (2) a nonempirical calculation of Tc. For these purposes, the author employs an extension of the DFT+DMFT (density-functional theory + dynamical mean-field theory). He constructs a realistic electron–phonon-coupled Hamiltonian with a newly formulated downfolding method. The Hamiltonian is analyzed by means of the extended DMFT. A notable aspect of the approach is that it requires only the crystal structure as a priori knowledge. Remarkably, the nonempirical calculat...
Alkali-doped Fullerides: Narrow-band Solids With Unusual Properties
Alkali-doped fullerides have attracted strong interest since their production became possible about fifteen years ago. This book presents recent work which may solve intriguing problems arising from a variety of remarkable properties. For example, these solids are superconductors with high transition temperatures, although the similarity between the electronic and phonon energy scales should suppress superconductivity. Moreover, the Ioffe-Regel condition for electrical conductivity is strongly violated. The book shows why superconductivity is nevertheless possible, owing to a local pairing mechanism. The Ioffe-Regel condition is derived quantum-mechanically, and it is explained why the underlying assumptions are violated for fullerides and high-Tc cuprates, for example. The book treats electronic and transport properties, reviewing theoretical and experimental results. It focuses on superconductivity, electrical conductivity and metal-insulator transitions, emphasizing the electron-electron and electron-phonon interactions as well as the Jahn-Teller effect.
Nuclear and Radiation Chemical Approaches to Fullerene Science
Preface by Sir Harold W. Kroto, FRS Although the discovery of C60 is now almost 15 years old and the extraction occurred 60 nearly ten years ago it is amazing that the range of spin-off research still seems to expand without limits. The birth of the Fullerenes has spawned fascinating research programmes in almost every area of chemistry and physics and this monograph explores a particularly interesting and important area - the behaviour of these pure carbon cages in the presence of high-energy radiation. The C molecules must also be in the space 60 between the stars (albeit in quantities too small to detect at this time) as the conditions in the atmospheres of some carbon stars appear to be ...
