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Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis
  • Language: en
  • Pages: 524

Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis

  • Type: Book
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  • Published: 2011-10-13
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  • Publisher: Elsevier

The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions of tons per year to a few grams per year. The diversity of catalysts is large and encompasses all the known categories of catalyst type: homogeneous, heterogeneous, and biological. This book summarizes the current status in these fields concentrating on rates, kinetics, and reaction mechanisms, but also covers broad topics including modeling, computational simulation, process concepts, spectroscopy and new catalyst development. The similarities and distinctions between the different reaction systems are compared, and the latest advances are described. - Comprehensive listing of epoxide products - Broad comparison of turnover frequencies of homogeneous, hetergeneous, main-group, biomimetic and biological catalysts - Analysis of the general strengths and weaknesses of varied catalytic systems - Detailed description of the mechanisms of reaction for classical and emerging catalysts

Catalysis
  • Language: en
  • Pages: 197

Catalysis

Our understanding of catalytic reactions exists at various levels which are mainly defined from detailed knowledge of reaction mechanism. When viewed in terms of the stoi chiometric reaction equation, most catalytic reactions are complex processes which occur via a sequence of elementary (i. e. irreducible) steps, and the elucidation ofthese elementary steps and the identification of a rate determining step (if one exists) constitutes the traditional approach to the problem of mechanism. The term "traditional" is not used here in a pejorative sense since mechanistic knowledge of this sort makes an important contribution to catalyst design, improvement, and optimization. This is the field whi...

Catalytic Ammonia Synthesis
  • Language: en
  • Pages: 462

Catalytic Ammonia Synthesis

The phenomenon of catalysis is found in many homogeneous and heterogeneous systems undergoing chemical change, where it effects the rates of approach to the equilibrium state in processes as diverse as those found in the stars, the earth's mantle, living organisms, and the various chemistries utilized by industry. The economies and the living standards of both developed and developing countries depend to varying degrees upon the efficacy of their chemical industries. Con sequently, this century has seen a wide exploration and expansion of catalytic chemistry together with an intensive investigation of specific, essential processes like those contributing to life-supporting agricultures. Prim...

Metal-Oxygen Clusters
  • Language: en
  • Pages: 318

Metal-Oxygen Clusters

Metal-Oxygen Clusters is the first book, providing an overview of the surface chemistry and catalytic properties of heteropoly oxometalates. After a brief look at the early knowledge of heteropoly oxometalates, the book discusses the synthesis, characterization, structure, bulk properties and stability of these materials. The remainder and the largest portion of the book explores the properties of these solids as catalysts in acid-catalyzed and oxidation processes in supported or unsupported forms. The book provides an up-to-date review of the methods for synthesizing heteropoly oxometalates of Keggin structure, techniques from spectroscopic through electrochemical to elemental analysis for ...

Letters to a Young Entrepreneur
  • Language: en
  • Pages: 110

Letters to a Young Entrepreneur

None

Surface Chemistry and Catalysis
  • Language: en
  • Pages: 392

Surface Chemistry and Catalysis

In 2001 Wyn Roberts celebrated both his 70th birthday and 50 years of working in surface science, to use the term "surface science" in its broadest meaning. This book aims to mark the anniversary with a contribution of lasting value, something more than the usual festschrift issue of a relevant journal. The book is divided into three sections: Surface Science, Model Catalysts and Catalysis, topics in which Wyn has always had interests. The authors for each chapter were chosen from some of the many eminent scientists who have worked with Wyn in various ways and are all internationally acknowledged as leaders in their field. The authors have produced authoritative reviews of their own specialties which together result in a book with an unrivalled combination of breadth and depth exploring the most recent developments in surface chemistry and catalysis.

Advances in Catalysis
  • Language: en
  • Pages: 275

Advances in Catalysis

Advances in Catalysis fills the gap between the journal papers and the textbooks across the diverse areas of catalysis research. For more than 60 years Advances in Catalysis has been dedicated to recording progress in the field of catalysis and providing the scientific community with comprehensive and authoritative reviews. This series in invaluable to chemical engineers, physical chemists, biochemists, researchers and industrial chemists working in the fields of catalysis and materials chemistry. - In-depth, critical, state-of-the-art reviews - Comprehensive, covers of all aspects of catalysis research

Hydrides of Metals and Metalloids
  • Language: en
  • Pages: 172

Hydrides of Metals and Metalloids

  • Type: Book
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  • Published: 1960
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  • Publisher: Unknown

None

Microdomains in Polymer Solutions
  • Language: en
  • Pages: 451

Microdomains in Polymer Solutions

In the first half of this century, great strides were made in under standing the behavior of polymers in dilute solutions or in the solid state. Concentrated solutions, on the other hand, were commonly regarded as mainly of interest to practitioners, being too complex for the rigorous application of statistical theory. Given the preoccupation with the isolated polymer molecule and the attendant focus on the state of infinite dilution, it is not surprising that aggregation, and inter-polymer associ ation in general, was the bugaboo of experimentalists. These attitudes have changed remarkably over the last few decades. The application of sealing theory to polymer solutions has stimulated inves...

Chemical Kinetics and Catalysis
  • Language: en
  • Pages: 290

Chemical Kinetics and Catalysis

to the Fundamental and Applied Catalysis Series Catalysis is important academically and industrially. It plays an essential role in the manufacture of a wide range of products, from gasoline and plastics to fertilizers and herbicides, which would otherwise be unobtainable or prohibitively expensive. There are few chemical-or oil-based material items in modem society that do not depend in some way on a catalytic stage in their manufacture. Apart from manu facturing processes, catalysis is finding other important and ever-increasing uses; for example, successful applications of catalysis in the control of pollution and its use in environmental control are certain to increase in the future. The...