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Thermodynamic Data on Oxides and Silicates
  • Language: en
  • Pages: 363

Thermodynamic Data on Oxides and Silicates

During the last thirty years profound developments in expe- rimental techniques to measure high temperature and pressu- res and thermodynamic properties of minerals have occurred. This technical development has been matched by an increased sophistication in applying theoretical methods to obtain new data or improve the quality of existing data. Using these newtechniques, Assessed Thermodynamic Data on Oxides and Silicates represents the successful attempt of the authors to develop an internally systematized data base which satis- fies the constraints of calorimetric measurements, phase equilibrium data, measured thermophysical properties of a phase, and heat capacities and entropies estimated from lat- tice vibrational models.

Thermodynamic Data
  • Language: en
  • Pages: 380

Thermodynamic Data

With the rapid development of fast processors, the power of a mini-super computer now exists in a lap-top box. Quite sophisticated techniques are be coming accessible to geoscientists, thus making disciplinary boundaries fade. Chemists and physicists are no longer shying away from computational mineral ogical and material science problems "too complicated to handle." Geoscientists are willing to delve into quantitative physico-chemical methods and open those "black boxes" they had shunned for several decades but with which had learned to live. I am proud to present yet another volume in this series which is designed to break the disciplinary boundaries and bring the geoscientists closer to their chemist and physicist colleagues in achieving a common goal. This volume is the result of an international collaboration among many physical geochemists (chemists, physicists, and geologists) aiming to understand the nature of material. The book has one common theme: namely, how to determine quantitatively through theory the physico-chemical parameters of the state of a solid or fluid.

Thermodynamic Data, Models, and Phase Diagrams in Multicomponent Oxide Systems
  • Language: en
  • Pages: 216

Thermodynamic Data, Models, and Phase Diagrams in Multicomponent Oxide Systems

This book involves application of the Calphad method for derivation of a self consistent thermodynamic database for the geologically important system Mg0- Fe0-Fe203-Alz03-Si02 at pressures and temperatures of Earth's upper mantle and the transition zone of that mantle for Earth. The created thermodynamic database reproduces phase relations at 1 bar and at pressures up to 30 GPa. The minerals are modelled by compound energy formalism, which gives realistic descriptions of their Gibbs energy and takes into account crystal structure data. It incorporates a detailed review of diverse types of experimental data which are used to derive the thermodynamic database: phase equilibria, calorimetric st...

Chemistry and Physics of Terrestrial Planets
  • Language: en
  • Pages: 416

Chemistry and Physics of Terrestrial Planets

The purpose of this volume is to present the latest planetary studies of an international body of scientists concerned with the physical and chemical aspects of terrestrial planets. In recent years planetary science has developed in leaps and bounds. This is a result of the application of a broad range of scientific disciplines, particularly physical and chemical, to an understanding of the information received from manned and unmanned space exploration. The first five chapters expound on many of the past and recent observations in an attempt to develop meaningful physical-chemical models of planetary formation and evolution. For any discussion of the chemical processes in the solar nebula, ...

Advances in Physical Geochemistry
  • Language: en
  • Pages: 355

Advances in Physical Geochemistry

The second volume of this series consists of three parts. Part I focuses on the research on intracrystalline reactions. This work, which began nearly two decades ago, is critically reviewed by Ghose and Ganguly in Chapter 1. Besides the review, the authors include some of their previously unpublished work to demonstrate how future research could aid in obtaining data on thermodynamics of solid solutions and in understanding the cooling history of igneous and metamorphic rocks. The latter is also the theme adopted by Kretz in the second chapter, which examines the redistribution of Fe and Mg in coexisting silicates during cooling. Chapter 3 contains new data on Fe-Mg distribution in clinopyro...

Mixtures and Mineral Reactions
  • Language: en
  • Pages: 291

Mixtures and Mineral Reactions

Considerable progress has been made in our understanding of the physicochemical evolution of natural rocks through systematic analysis of the compositional properties and phase relations of their mineral assemblages. This book brings together concepts of classical thermodynamics, solution models, and atomic ordering and interactions that constitute a major basis of such analysis, with appropiate examples of application to subsolidus petrological problems. This book is written for an audience with a senior undergraduate level background in chemistry. Derivations of fundamental thermodynamic relations which are in need of reemphasis and clarification are presented.

Thermodynamics of Rock-Forming Crystalline Solutions
  • Language: en
  • Pages: 202

Thermodynamics of Rock-Forming Crystalline Solutions

None

Kinetics and Equilibrium in Mineral Reactions
  • Language: en
  • Pages: 280

Kinetics and Equilibrium in Mineral Reactions

With contributions by numerous experts

Ecosystem Dynamics in a Polar Desert
  • Language: en
  • Pages: 224

Ecosystem Dynamics in a Polar Desert

Presents information from the primary abiotic forces defining the system, and from the present hydrology, biogeochemistry and physics of major sites of organic carbon production of the McMurdo Dry Valleys. Additionally, research on the physical, chemical, and biological properties of the dry valley soils is included. The role of environmental management in long-term ecological studies is also addressed. The accompanying CDROM provides details and scale to visualize the McMurdo Dry Valleys from an ecosystem perspective.

The English Language Amendment
  • Language: en
  • Pages: 292