Welcome to our book review site go-pdf.online!
You may have to Search all our reviewed books and magazines, click the sign up button below to create a free account.
N Nitrogen
This volume deals with binary nitrogen-hydrogen compounds having two, three, or more nitrogen atoms (with the exception of hydrazine) and with compounds composed of nitrogen, hydrogen, and noble gases. The important species containing two nitrogen atoms, N2H, N2H+, N2H2, and N2H3 are described in the first part of this volume. Next, chains and cycles consisting of three nitrogen atoms are covered. Among them hydrogen azide or hydrozoic acid, HN3, is the most extensively studied nitrogen-hydrogen compound described in this volume. With increasing number of nitrogen atoms, the thermochmical stability declines. There is, however, a considerable amount of information on molecules with up to nine linked nitrogen atoms. Several of these binary nitrogen-hydrogen compounds could only be isolated in the form of organic derivatives. In that case, data available for the organic derivatives were included if they were characteristic for the particular unsubstituted N-H parent compound.
N Nitrogen
"Nitrogen" Suppt. Vol. B 1 describes the compounds of nitrogen with noble gases and, in the major part, binary compounds composed of one nitrogen atom and hydrogen. Nitrogen hydrogen compounds with two and more nitrogen atoms are covered in "Nitrogen" Suppt. Vol. 82. There is some information on various nitrogen-noble gas species, to a large extent because of the interest in their bonding behavior. Experimental data have been obtained chiefly for some singly charged cations, particularly those formed by argon Like ArN + and ArNi. The existence of others has only been established by mass spectrometry. The binary compounds of nitrogen and hydrogen comprise NH, NH , NH , NH , the corre 2 4 5 sp...
Compounds with Fluorine and Chlorine
The volume describes all compounds that consist of bromine and fluorine and/or chlorine and may additionally contain noble gases, hydrogen, oxygen, and nitrogen. The description of chemical and physical properties of binary compounds between bromine and fluorine takes up most of the volume, because this class of compounds includes BrF3 and BrF5 which have considerable technical interest. Especially the the oxidizing and fluorinating properties of BrF3 make it a convenient reactant for the preparation of inorganic fluorides. On the other hand, the diatomic molecule BrF is well-characterized by spectroscopic methods, but its chemistry is less known because of its instability. Other neutral species, such as Br2F, Br2F2, BrF2, and BrF6, only exist in matrices at low temperatures, and the existence of BrF4 and BrF7 is even doubted. Some of the ions, including BrF2+, BrF2-, Br3F10-, BrF4+, BrF4-, BrF6+, and BrF6-, can be stabilized as salts.
Bromine: The element
None
Compounds with Oxygen and Nitrogen
The volume describes the chemical and physical properties of the approximately 80 known bromine compounds and ions which contain oxygen and/or nitrogen, and which may include hydrogen as well. The class of bromine-oxygen and bromine-oxygen-hydrogen compounds comprises several well-known species. Their description accounts for approximately three-quarters of the volume. The BrO radical and the BrO3 ion are the most and best studied among all binary bromine-oxygen species. BrO was recently recognized to play a role in some reaction sequences depleting the ozone concentration in the stratosphere. Bromate-ion-driven chemical oscillator systems have attracted much interest in recent decades. Thus data on single reaction steps which involve BrO3, BrO2, and the oxoacides of bromine - HBrO, HBrO2, and HBrO3 - are reviewed in detail; a comprehensive description of the oscillating systems, however, is beyond the scope of this volume. The remaining one-quarter of the volume is devoted to bromine-nitrogen and bromine-nitrogen-oxygen compounds. Bromine azide and nitrosyl bromide are the most comprehensively studied of these, accounting for almost half of this section.
DUZ Nachrichten
None
MPG Spiegel
None
