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Among the topics of interest to organic chemists today are the versatility and uniqueness of electrolysis procedures in organic synthesis, as well as the latest advances in methodology, including basic concepts for the design of electrolysis conditions and apparatus. The International Symposium on Electroorganic Synthesis met in Kurashiki, Japan, in September 1997 for lectures on all aspects of current research in the field. This volume comprising the papers from the symposium consists of two parts. Part I, Electrooxidation, includes papers on alcohols and phenols, olefins and aromatics, halogenation, polymers, and electrodes, among others. Included in Part II, Electroreduction, are papers on carbonyl compounds, halogen-containing compounds, reaction with EG bases, and metal complexes. The novel trends presented here will be of special interest to researchers and graduate students in electroorganic chemistry and are a valuable resource for all organic chemists.
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L'OBJECTIF PRINCIPAL DE CE TRAVAIL EST L'ETUDE DE NOUVEAUX TETRATHIAFULVALENES ET DITHIAFULVENES. NOUS DECRIVONS DES SYNTHESES ORIGINALES DE TETRATHIAFULVALENES PRESENTANT DEUX CYCLES DITHIOLES SEPARES PAR UN MOTIF CONJUGUE. NOUS PREPARONS EN PARTICULIER POUR LA PREMIERE FOIS DES COMPOSES DE CE TYPE POSSEDANT DES MOTIFS CONJUGUES AZOTES. NOUS COMPARONS UN COMPLEXE PAR TRANSFERT DE CHARGE OBTENU A PARTIR DE L'ANTHRACENE DIYLIDENE BIS 1,3-DITHIOLE ET DU TETRACYANOQUINODIMETHANE AVEC UN COMPLEXE VOISIN DECRIT DANS LA LITTERATURE. NOUS PROPOSONS EGALEMENT UNE NOUVELLE VOIE D'ACCES AUX DENDRALENES ET NOUS CONTRIBUONS A LA SYNTHESE DE TETRATHIAFULVALENES DISSYMETRIQUES EN ETUDIANT TROIS VOIES D'ACCES A CES COMPOSES. DE NOMBREUX DITHIAFULVENES PUSH-PULL, EVENTUELLEMENT AMPHIPHILES SONT EGALEMENT PREPARES PAR DES SYNTHESES ORIGINALES. NOUS METTONS EN EVIDENCE L'INTERET EN OPTIQUE NON LINEAIRE DES DITHIAFULVENES SUBSTITUES PAR DES DONNEURS