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Advances in Organometallic Chemistry
Advances in Organometallic Chemistry
Catalytic Polymerization of Cycloolefins
This book covers the most important topics concerning cationic Ziegler-Natta and ring-opening metathesis polymerization of cycloolefins. The work describes the major pathways that cycloolefins can follow under the action of specific catalytic systems, essentially vinyl and ring-opening polymerization, both reaction types allowing the manufacture of distinct products with wide applicability in modern technologies. The comprehensive data available on this subject are logically and systematically selected and reviewed throughout 18 chapters, according to the basic catalytic processes involved, types of monomers and catalysts employed, reaction conditions and application fields. The modern trend...
How to live and survive in Zambezian open forest (Miombo ecoregion)
In the Miombo ecoregion (2,865,000 km² or 9.1% of Africa), the Zambezian open forest constitutes the main vegetation unit. It extends to no less than eight countries, from Burundi in the North to South Africa in the South, and from Angola in the West to Mozambique in the East. The austral part of Africa's open forests falls within the Zambezian Regional Center of Endemism outlined by White in 1983. This book focuses mainly on the wetter Zambezian Miombo woodlands. Also patches of mosaic Zambezian dry evergreen forests and small areas of grasslands on Kalahari sands are incorporated in the study. The aim of this book is to gather together the amazing local environment knowledge of Zambezian ...
Olefin Metathesis and Polymerization Catalysts
Olefin metathesis reaction can be considered as one of the most successful organic reactions with many applications in the low molecular weight range and also in the polymer field. The use of catalysts with their selective and effective transformation properties in olefin metathesis I polymerization systems is a growing interest. There has been great effort and competition in developing active and commercially useful catalysts. The main aim of this ASI was to gather several research groups and also the people from industry. to present existing knowledge and latest results in the field. A wide range of topics through homogeneous and heterogeneous aspects have been considered. Attention has be...
Fundamentals of Polymerization
Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and dispersion polymerization (in polar solvents). Apart from the developments in the chemistry of polymerization, methods have been developed for the evaluation of highly reliable rate constants of propagation in radical as well as cationic polymerization. All these have revolutionized the field of synthetic polymer chemistry. In the book, fundamentals of both the new and old polymerization chemistry have been dealt with. The new chemistry has been given nearly equal space along with the old.
