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Understanding Voltammetry (Fourth Edition)
The power of electrochemical measurements in respect of thermodynamics, kinetics and analysis is widely recognised but the subject can be unpredictable to the novice even if they have a strong physical and chemical background, and most especially if they wish to pursue quantitative measurements. Accordingly, some significant experiments are perhaps wisely never attempted, while the literature is sadly replete with flawed attempts at rigorous voltammetry.This textbook considers how to go about designing, explaining and interpreting experiments centred on various forms of voltammetry (cyclic, microelectrode, hydrodynamic, etc.). The reader is assumed to have knowledge of physical chemistry equ...
Understanding Voltammetry
Preface to the second edition -- Preface to the first edition - Introduction -- Mathematical model of an electrochemical system -- Numerical solution of the model system -- Diffusion-only electrochemical problems in one-dimensional systems -- First-order chemical kinetic mechanisms -- Second-order chemical kinetic mechanisms -- Electrochemical simulation in weakly supported media -- Hydrodynamic voltammetry -- Two-dimensional systems: microdisc electrodes -- Heterogeneous surfaces -- Stochastic electrochemistry.
Surface Photovoltage Analysis of Photoactive Materials
Symbols and abbreviations -- Light-induced charge separation and surface - photoactive -- Measurement techniques of surface photovoltage signals -- practical aspects of surface photovoltage measurements -- Random walk simulation of surface photovoltage signals in small systems -- Selected applications of surface photovoltage techniques.
