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Study of the Kinetics of the Reaction Between Uranium, H2, HD and D2
The kinetics of the reactions between uranium metal, H2, HD and D2 have been examined. There is strong evidence that the reaction involves several steps of which activated adsorption of the gas by the metal is the rate governing process. Rate constants have been determined for the over-all processes in the temperature range 27.5 deg to 75 deg C. Energies of activation which are of reasonable magnitude have been calculated being 10,200 calories for the process involving D2, 8,500 calories for the process involving HD and 8,200 calories for the process involving H2. From a consideration of the zero point energies for these three molecular species of hydrogen, these results follow in the right ...
